Microstructure, kinetics, and transport in oil-in-water microemulsion polymerizations

被引：19
|
作者：
O'Donnell, Jennifer [1 ]
Kaler, Eric W. [1 ]
机构：
[1] Univ Delaware, Dept Chem Engn, Ctr Mol & Engn Thermodynam, Newark, DE 19716 USA
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2007年 / 28卷 / 14期
关键词：
kinetics (polym.); microemulsion polymerization; microstructure; thermodynamics; TRANSFER RADICAL POLYMERIZATION; FRAGMENTATION CHAIN TRANSFER; ANGLE NEUTRON-SCATTERING; VINYL-ACETATE; METHYL-METHACRYLATE; EMULSION POLYMERIZATION; STYRENE POLYMERIZATION; BUTYL ACRYLATE; DODECYLTRIMETHYLAMMONIUM BROMIDE; SURFACTANT CONCENTRATION;
D O I：
10.1002/marc.200700055
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The kinetics of microemulsion polymerization depend on the structure of the initial microemulsion and the transport of species between the aqueous domain, the micelles, and the polymer particles. The water solubility of the monomer and the proximity of the initial microemulsion composition to a phase boundary are Key considerations tor studying microemulsion polymerization kinetics and producing the desired products. Complications frequently arise in the synthesis of copolymers or the incorporation of controlled polymerization mechanisms because of the compartmentalized nature of microemulsion polymerizations.
引用
收藏
页码：1445 / 1454
页数：10
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