Fast electrochemically induced translation of the ring in a copper-complexed [2]rotaxane: The biisoquinoline effect

被引：59

作者：

Durola, Fabien ^{[1
]}

Sauvage, Jean-Pierre ^{[1
]}

机构：

[1] Univ Strasbourg, UMR 7177, CNRS, Lab Chim Organo Minerale,Inst Chim, 1 Rue Blaise Pascal, F-67000 Strasbourg, France

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 19期

关键词：

chelates; coordination modes; copper; molecular devices; rotaxanes;

D O I：

10.1002/anie.200604815

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

On the fast track: A molecular shuttle has been synthesized, whose ring incorporates an 8,8′-diphenyl-3,3′-biisoquinoline chelating unit. This unit is both endocyclic and not sterically hindering (see picture), which leads to remarkably fast shuttling motions (milliseconds) of the copper-complexed ring between two stations. (Chemical Equation Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3537 / 3540

页数：4

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