Using rare earth ions to improve the luminescence properties of the defect-related luminescent material Zn3Al2Ge2O10

被引:8
作者
Bai, Qiongyu [1 ]
Wang, Zhijun [1 ]
Li, Panlai [1 ]
Xu, Shuchao [1 ]
Li, Ting [1 ]
Yang, Zhiping [1 ]
机构
[1] Hebei Univ, Coll Phys Sci & Technol, Hebei Key Lab Opt Elect Informat & Mat, Baoding 071002, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
BLUISH-WHITE EMISSION; TUNABLE LUMINESCENCE; LONG AFTERGLOW; PHOSPHORS; LIGHT; MONODISPERSE; EU3+; CA; TM; DY;
D O I
10.1039/c7nj00181a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Herein, Zn3Al2Ge2O10 was synthesized by a high-temperature solid-state method, and a weak white emission ranging from 350 to 600 nm was observed. To enhance the white emission intensity of Zn3Al2Ge2O10, rare earth ions (Eu3+, Ce3+, Dy3+, and Tb3+) were introduced into Zn3Al2Ge2O10. The results show that the white emission intensity of Zn3Al2Ge2O10 is enhanced by doping rare earth ions, which is ascribed to the increased oxygen vacancy V ''(o). Especially, Eu3+ ions can effectively enhance the white emission intensity of Zn3Al2Ge2O10 as compared to other rare earth ions (Ce3+, Dy3+, and Tb3+) when doped in Zn3Al2Ge2O10, and the intensity is maximum when the doping concentration reaches 6 mol%. The results indicate that the luminescence properties of the defect-related luminescent material Zn3Al2Ge2O10 can be improved by doping rare earths ions.
引用
收藏
页码:7400 / 7406
页数:7
相关论文
共 35 条
[1]   Using Ca2+ ions to induce the long afterglow and bluish white emission of red emitting phosphor Zn3Al2Ge2O10:Cr3+ [J].
Bai, Qiongyu ;
Li, Panlai ;
Wang, Zhijun ;
Li, Ting ;
Xu, Shuchao ;
Yang, Zhiping .
MATERIALS & DESIGN, 2016, 91 :28-36
[2]   Host-sensitized white light-emitting phosphor MgY4Si3O13:Dy3+ with satisfactory thermal properties for UV-LEDs [J].
Ci, Zhipeng ;
Guan, Runnan ;
Jin, Lijun ;
Han, Lili ;
Zhang, Jiachi ;
Ma, Ji ;
Wang, Yuhua .
CRYSTENGCOMM, 2015, 17 (27) :4982-4986
[3]   Host-sensitized luminescence properties of KLa5O5(VO4)2:Eu3+ for solid-state lighting applications [J].
Colmont, Marie ;
Saitzek, Sebastien ;
Katelnikovas, Arturas ;
Kabbour, Houria ;
Olchowka, Jacob ;
Roussel, Pascal .
JOURNAL OF MATERIALS CHEMISTRY C, 2016, 4 (30) :7277-7285
[4]   Thermally stimulated luminescence from x-irradiated porous silicon [J].
Cooke, DW ;
Bennett, BL ;
Farnum, EH ;
Hults, WL ;
Muenchausen, RE ;
Smith, JL .
APPLIED PHYSICS LETTERS, 1997, 70 (26) :3594-3596
[5]   Ligand-Passivated Eu:Y2O3 Nanocrystals as a Phosphor for White Light Emitting Diodes [J].
Dai, Qilin ;
Foley, Megan E. ;
Breshike, Christopher J. ;
Lita, Adrian ;
Strouse, Geoffrey F. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (39) :15475-15486
[6]   Trap states of tris-8-(hydroxyquinoline) aluminum and naphthyl-substituted benzidine derivative using thermally stimulated luminescence [J].
Forsythe, EW ;
Morton, DC ;
Tang, CW ;
Gao, YL .
APPLIED PHYSICS LETTERS, 1998, 73 (11) :1457-1459
[7]   Intense red light emission of Eu3+-doped LiGd(PO3)4 for mercury-free lamps and plasma display panels application [J].
Han, Bing ;
Liang, Hongbin ;
Ni, Haiyong ;
Su, Qiang ;
Yang, Guangtao ;
Shi, Junyan ;
Zhang, Guobin .
OPTICS EXPRESS, 2009, 17 (09) :7138-7144
[8]   Native Point Defects in CaS: Focus on Intrinsic Defects and Rare Earth Ion Dopant Levels for Up-converted Persistent Luminescence [J].
Huang, Bolong .
INORGANIC CHEMISTRY, 2015, 54 (23) :11423-11440
[9]   A novel approach to monodisperse, luminescent silica spheres [J].
Jakob, Adam M. ;
Schmedake, Thomas A. .
CHEMISTRY OF MATERIALS, 2006, 18 (14) :3173-3175
[10]   Enhanced Yellow-to-Orange Emission of Si-Doped Mg3Y2Ge3O12:Ce3+ Garnet Phosphors for Warm White Light-Emitting Diodes [J].
Jiang, Ziqiang ;
Wang, Yuhua ;
Wang, Linshui .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (05) :J155-J158