Simple expressions for the heat capacities of elemental solids

被引：1
作者：
Iglesias-Silva, GA
Hall, KR [1 ]
机构：
[1] Inst Tecnol Celaya, Dept Ingn Quim, Guanajuato 38010, Mexico
[2] Texas A&M Univ, Dept Chem Engn, College Stn, TX 77843 USA
来源：
CHEMICAL ENGINEERING COMMUNICATIONS | 1997年 / 158卷
关键词：
Debye; Churchill-Usagi; heat capacity; elemental solid;
D O I：
10.1080/00986449708936588
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
We have developed an expression for the heat capacity of solids using the asymptotic behavior described by Debye. This new correlation has the same accuracy as the Debye expression, but uses an empirical constant to avoid numerical integration. The average percentage error for 19 substances is 3.92%. Adding a term to address low temperatures reduces the average percentage error to 2.76% for 13 substances. The experimental error for the measurements appears to be in the range of 1-5% for the elements selected.
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页码：193 / 199
页数：7
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