First electrochemical synthesis of network silane and silane-germane copolymers:: (C6H11Si)x(PhSi)y and (C6H11Si)x(PhGe)y

被引：22

作者：

Huang, K ^{[1
]}

Vermeulen, LA ^{[1
]}

机构：

[1] So Illinois Univ, Dept Chem & Biochem, Carbondale, IL 62901 USA

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 02期

关键词：

D O I：

10.1039/a705254e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An electrochemical technique is demonstrated for the synthesis of Si-Si and Si-Ge network copolymers poly(cyclohexylsilyne-co-phenylsilyne) and poly(cyclohexylsilyne-co-phenylgermyne); the molecular mass distributions of the electrochemically prepared polymers are more narrow in comparison to similar polymers prepared by the Wurtz coupling reaction.

引用

页码：247 / 248

页数：2

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