Synthesis of a 2D phosphorus material in a MOF- based 2D nano- reactor

被引：17

作者：

Li, Ming ^{[1
]}

Ma, Chuang ^{[1
]}

Liu, Xiong ^{[2
]}

Su, Jun ^{[3
]}

Cui, Xiaofeng ^{[4
]}

He, Yunbin ^{[5
]}

机构：

[1] Hubei Univ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Key Lab Synth & Applicat Organ Funct Mol,Minist E, Hubei Key Lab Polymer Mat,Coll Chem & Chem Engn, Wuhan 430062, Hubei, Peoples R China

[2] Carl Zeiss Microscopy GmbH, Carl Zeiss Str 22, D-73447 Oberkcohen, Germany

[3] Huazhong Univ Sci & Technol, Wuhan Natl Lab Optoelect, Luoyu Rd 1037, Wuhan 430074, Peoples R China

[4] Wuhan Univ Technol, Sch Chem Chem Engn & Life Sci, Wuhan 430070, Hubei, Peoples R China

[5] Hubei Univ, Sch Mat Sci & Engn, Wuhan 430062, Hubei, Peoples R China

来源：

CHEMICAL SCIENCE | 2018年 / 9卷 / 27期

关键词：

METAL-ORGANIC FRAMEWORKS; 2-DIMENSIONAL POLYMER; BLACK PHOSPHORUS; NANOMATERIALS; PERFORMANCE; NANOPARTICLES; EXFOLIATION; ADSORPTION; NANOSHEETS; GRAPHENE;

D O I：

10.1039/c8sc01439f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesis of two dimensional (2D) materials mainly relies on interface-templates, exfoliation of layered crystals and surfactant-assistance. Here we have realized another strategy of polymerization in a 2D nano-reactor. As an application of this strategy, a 2D nano-reactor was constructed within a new pillar-layer metal organic framework (MOF) and in this nano-reactor a moderately stable 2D phosphorus material was synthesized from white phosphorus (P-4). Our research may provide a new approach for the synthesis of various 2D materials.

引用

页码：5912 / 5918

页数：7

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