Metal-free O-H/C-H difunctionalization of phenols by o-hydroxyarylsulfonium salts in water

被引：40

作者：

Chen, Dengfeng ^{[1
]}

Feng, Qingyuan ^{[1
]}

Yang, Yunqin ^{[1
]}

Cai, Xu-Min ^{[1
]}

Wang, Fei ^{[1
]}

Huang, Shenlin ^{[1
]}

机构：

[1] Nanjing Forestry Univ, Coll Chem Engn, Jiangsu Key Lab Biomass Based Green Fuels & Chem, Nanjing 210037, Jiangsu, Peoples R China

来源：

CHEMICAL SCIENCE | 2017年 / 8卷 / 02期

关键词：

ESTROGEN-RECEPTOR LIGANDS; CATALYZED CROSS-COUPLINGS; MIXED PHOSPHORUS/SULFUR LIGANDS; ARYL HALIDES; DIHYDROBENZOXATHIIN SERAMS; PUMMERER REACTION; BOND FORMATION; YLIDE TRANSFER; SIDE-CHAINS; C-S;

D O I：

10.1039/c6sc04504a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An environmentally benign method for C-H/O-H difunctionalization of phenols with sulfoxides under mild conditions has been developed. The reaction process is mediated by an electrophilic aromatic substitution and subsequent selective aryl or alkyl migration, involving C-S and C-O bond formations with broad substrate scope.

引用

页码：1601 / 1606

页数：6

共 72 条

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