A Rare Earth Metal-Organic Framework with H6TTAB Ligand

被引:1
作者
Han Zongsu [1 ]
Yu Xiaoyong [1 ]
Min Hui [1 ]
Shi Wei [1 ]
Cheng Peng [1 ]
机构
[1] Nankai Univ, Coll Chem, Tianjin 300071, Peoples R China
来源
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2022年 / 43卷 / 01期
基金
中国国家自然科学基金;
关键词
Rare earth; Metal-organic framework; Fluorescence property; CHEMISTRY; DESIGN; MOFS;
D O I
10.7503/cjcu20210342
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A rare, earth metal-organic framework (MOF), Eu-TTAB. formed by the coordination of 1,2,3-tricarboxyl(1', 2' ,3'-tricarboxylazophenyl) -benzene (1-1 6 TTAB) and linear tetranuclear europium coordination unit with a {4(14)center dot 6(2n)center dot 8(11)} {4(3)}(2){4(5)center dot 6} topology, was synthesized by hydrothermal method. Eu-TTAB showed excellent thermal stability and solvent stability. Flourescence property of Eu-TTAB under UV excitation was studied. Furthermore, the fluorescence of Eu-TTAB can be tuned by terbium ions as the second emission center and silver ions to enhance the luminescence intensities.
引用
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页数:6
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