Synthesis, characterization and crystal structure of bis(p-fluorobenzaldehyde salicylhydrazone) nickel (II)

被引：0

作者：

Zhang Shu-Ping ^{[1
]}

Liu Zhao-Di ^{[1
]}

Chen Shui-Sheng ^{[1
]}

Wei Ying ^{[1
]}

Shao Si-Chang ^{[1
]}

机构：

[1] Fuyang Normal Coll, Dept Chem, Fuyang 236041, Anhui, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 23卷 / 06期

关键词：

p-fluorobenzaldehyde salicylhydrazone; nickel(II) complex; crystal structure; synthesis;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A nickel(II) complex Ni(C14H10N2O2F)(2) was synthesized from p-fluorobenzaldehyde salicylhydrazone and Ni(CH3COO)(2)center dot 4H(2)O and crystallized by diffusion,the structure of which was characterized by IR spectrum, H-1 NMR, and X-ray single-crystal diffraction. The complex crystallizes in monoclinic space group C2/c with a=2.460 6(2) nm, b=0.774 1(1) nm, c=1.534 9(1) nm, beta=122.300(1)degrees, and V=2.471 1(4), Z=8, D-c=1.541 g.cm(-3). We reported the IR, H-1 NMR, crystal structure. CCDC: 638652.

引用

页码：1069 / 1071

页数：3

共 7 条

[1] Antitumour copper(II) salicylaldehyde benzoylhydrazone (H(2)sb) complexes: physicochemical properties and the single-crystal X-ray structures of [{Cu(H(2)sb)(CCl3CO2)(2)}(2)] and [{Cu(Hsb)(ClO4)(C2H5OH)}(2)] and the related salicylaldehyde acetylhydrazone (H(2)sa) complex, [Cu(Hsa)Cl(H2O)]center dot H2O [J].

Ainscough, EW ;

Brodie, AM ;

Dobbs, AJ ;

Ranford, JD ;

Waters, JM .

INORGANICA CHIMICA ACTA, 1998, 267 (01) :27-38

[2] High nuclearity nickel compounds with three, four or five metal atoms showing antibacterial activity [J].

Alexiou, M ;

Tsivikas, I ;

Dendrinou-Samara, C ;

Pantazaki, AA ;

Trikalitis, P ;

Lalioti, N ;

Kyriakidis, DA ;

Kessissoglou, DP .

JOURNAL OF INORGANIC BIOCHEMISTRY, 2003, 93 (3-4) :256-264

[3] Amide hydrolysis effected by a hydroxo-bridged dinickel(II) complex: Insights into the mechanism of urease [J].

Barrios, AM ;

Lippard, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (50) :11751-11757

[4] THE CRYSTAL-STRUCTURE OF UREASE FROM KLEBSIELLA-AEROGENES [J].

JABRI, E ;

CARR, MB ;

HAUSINGER, RP ;

KARPLUS, PA .

SCIENCE, 1995, 268 (5213) :998-1004

[5] Modeling the coordination mode of hydroxamate inhibitors in urease:: preparation, X-ray crystal structure and spectroscopic characterization of the dinuclear complex [Ni2(O2CMe)(LH)2(tmen)2](O2CMe)•0.9H2O•0.6EtOH (LH2 = benzohydroxamic acid; tmen = N, N, N′, N′-tetramethylethylenediamine) [J].

Milios, CJ ;

Manessi-Zoupa, E ;

Perlepes, SP .

TRANSITION METAL CHEMISTRY, 2002, 27 (08) :864-873

[6]

Yin H, 2002, CHINESE J INORG CHEM, V18, P269

[7] 4-Fluorobenzaldehyde salicylhydrazone [J].

Zhang, Y ;

Zhang, SP ;

Wu, YY ;

Shao, SC .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 :O119-O120

← 1 →