A Flexible Method for Covalent Double Functionalization of Graphene Oxide

被引：63
|
作者：
Guo, Shi [1 ]
Nishina, Yuta [2 ,3 ]
Bianco, Alberto [1 ]
Menard-Moyon, Cecilia [1 ]
机构：
[1] Univ Strasbourg, CNRS, UPR 3572, Immunol Immunopathol & Therapeut Chem, F-67000 Strasbourg, France
[2] Okayama Univ, Grad Sch Nat Sci & Technol, Kita Ku, Okayama 7008530, Japan
[3] Okayama Univ, Res Core Interdisciplinary Sci, Kita Ku, Okayama 7008530, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2020年 / 59卷 / 04期
关键词：
graphene; materials science; Michael addition; small ring systems; surface chemistry; ATTACHMENT; REDUCTION; CHEMISTRY; CARRIERS;
D O I：
10.1002/anie.201913461
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A method for the double functionalization of graphene oxide (GO) under mild alkaline conditions has been developed. Two functional groups were covalently linked to GO in two steps: the first group was attached by an epoxide ring-opening reaction and the second, bearing an amine function, was covalently conjugated to benzoquinone attached to the GO. The doubly functionalized GO was characterized by several techniques, confirming the sequential covalent modification of the GO surface with two different functional groups. This method is straightforward and the reaction conditions are mild, allowing preservation of the structure and properties of GO. This strategy could be exploited to prepare multifunctional GO conjugates with potential applications in many fields ranging from materials science to biomedicine.
引用
收藏
页码：1542 / 1547
页数：6
相关论文
共 50 条
  • [21] Covalent organic functionalization of graphene nanosheets and reduced graphene oxide via 1,3-dipolar cycloaddition of azomethine ylide
    Basta, Luca
    Moscardini, Aldo
    Fabbri, Filippo
    Bellucci, Luca
    Tozzini, Valentina
    Rubini, Silvia
    Griesi, Andrea
    Gemmi, Mauro
    Heun, Stefan
    Veronesi, Stefano
    NANOSCALE ADVANCES, 2021, 3 (20): : 5841 - 5852
  • [22] Rapid Functionalization of Graphene Oxide in Water
    McGrail, Brendan T.
    Rodier, Bradley J.
    Pentzer, Emily
    CHEMISTRY OF MATERIALS, 2014, 26 (19) : 5806 - 5811
  • [23] Structural characterization of Graphene Oxide and Reduced Graphene Oxide used as counter electrode in flexible DSSC
    Hurtado-Morales, Mikel.
    Pazos-Alonso, Jhon E.
    Alejandro Garcia-Fox, M.
    Castarlenas, Sonia.
    Tellez, Carlos.
    Coronas, Joaquin.
    2018 IEEE 7TH WORLD CONFERENCE ON PHOTOVOLTAIC ENERGY CONVERSION (WCPEC) (A JOINT CONFERENCE OF 45TH IEEE PVSC, 28TH PVSEC & 34TH EU PVSEC), 2018, : 1116 - 1121
  • [24] A non-covalent functionalization of copper tetraphenylporphyrin/chemically reduced graphene oxide nanocomposite for the selective determination of dopamine
    Karuppiah, Chelladurai
    Sakthinathan, Subramanian
    Chen, Shen-Ming
    Manibalan, Kesavan
    Chen, Sin-Ming
    Huang, Sheng-Tung
    APPLIED ORGANOMETALLIC CHEMISTRY, 2016, 30 (01) : 40 - 46
  • [25] Unifying Principles of the Reductive Covalent Graphene Functionalization
    Abellan, Gonzalo
    Schirowski, Milan
    Edelthalhammer, Konstantin F.
    Fickert, Michael
    Werbach, Katharina
    Peterlik, Herwig
    Hauke, Frank
    Hirsch, Andreas
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (14) : 5175 - 5182
  • [26] Solvent-free one-step covalent functionalization of graphene oxide and nanodiamond with amines
    Alzate-Carvajal, Natalia
    Basiuk, Elena V.
    Meza-Laguna, Victor
    Puente-Lee, Ivan
    Farias, Mario H.
    Bogdanchikova, Nina
    Basiuk, Vladimir A.
    RSC ADVANCES, 2016, 6 (114): : 113596 - 113610
  • [27] Scalable and site specific functionalization of reduced graphene oxide for circuit elements and flexible electronics
    Soni, Mahesh
    Kumar, Pawan
    Pandey, Juhi
    Sharma, Satinder Kumar
    Soni, Ajay
    CARBON, 2018, 128 : 172 - 178
  • [28] Highly selective covalent organic functionalization of epitaxial graphene
    Bueno, Rebeca A.
    Martinez, Jose I.
    Luccas, Roberto F.
    Ruiz del Arbol, Nerea
    Munuera, Carmen
    Palacio, Irene
    Palomares, Francisco J.
    Lauwaet, Koen
    Thakur, Sangeeta
    Baranowski, Jacek M.
    Strupinski, Wlodek
    Lopez, Maria F.
    Mompean, Federico
    Garcia-Hernandez, Mar
    Martin-Gago, Jose A.
    NATURE COMMUNICATIONS, 2017, 8
  • [29] Covalent Functionalization of Graphene for the Enhancement of Thermophysical Properties in Nanofluids
    Selvaraj, Vishnuprasad
    Senthilkumar, Karthick
    Krishnan, Haribabu
    CHEMICAL ENGINEERING & TECHNOLOGY, 2021, 44 (05) : 811 - 818
  • [30] Work function engineering of graphene oxide via covalent functionalization for organic field-effect transistors
    Ji, Seulki
    Min, Bok Ki
    Kim, Seong K.
    Myung, Sung
    Kang, Minseo
    Shin, Hong-Suk
    Song, Wooseok
    Heo, Jungseok
    Lim, Jongsun
    An, Ki-Seok
    Lee, Ill-Young
    Lee, Sun Sook
    APPLIED SURFACE SCIENCE, 2017, 419 : 252 - 258
12345