Layer by Layer Construction of Metal-Organic Molecule Bilayer on a Au(111) Surface

被引：3
|
作者：
Qu, Deyu [1 ]
Ito, Mikio [1 ]
Noguchi, Hidenori [1 ,2 ]
Uosaki, Kohei [1 ,3 ]
机构：
[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Phys Chem Lab, Sapporo, Hokkaido 0600810, Japan
[2] Natl Inst Mat Sci, Int Ctr Mat Nanoarchitecton MANA, Tsukuba, Ibaraki 3050044, Japan
[3] NIMS, Int Ctr Mat Nanoarchitecton MANA Satellite, Sapporo, Hokkaido 0600810, Japan
来源：
CHEMISTRY LETTERS | 2010年 / 39卷 / 02期
关键词：
SELF-ASSEMBLED MONOLAYER; SUM-FREQUENCY GENERATION; REDUCTIVE DESORPTION; ETHANOL SOLUTION; SPECTROSCOPY; DEPOSITION; DECANETHIOL;
D O I：
10.1246/cl.2010.110
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A thiolate self-assembled monolayer (SAM) was formed oil a metallized dithiol SAM, resulting in a new kind of metal-organic molecule bilayer. 1,6-Hexanedithiol (HDT) was adsorbed on a Au(111) surface followed by adsorption and electrochemical reduction of AuCl4- Oil the HDT SAM, and then by adsorption of 1-decanethiol. The formation of the bilayer was confirmed by Fourier transform infrared spectroscopy, sum frequency generation, and electrochemical measurements.
引用
收藏
页码：110 / 111
页数：2
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