Alkaloidosteroids from the starfish Lethasterias nanimensis chelifera

被引：29

作者：

Kicha, AA ^{[1
]}

Ivanchina, NV ^{[1
]}

Kalinovsky, AI ^{[1
]}

Dmitrenok, PS ^{[1
]}

Stonik, VA ^{[1
]}

机构：

[1] Russian Acad Sci, Pacific Inst Bioorgan Chem, Far Eastern Branch, Vladivostok 159, Russia

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 09期

基金：

俄罗斯基础研究基金会;

关键词：

starfish metabolites; steroids; alkaloids; salsolinol; MTCA;

D O I：

10.1016/S0040-4039(03)00088-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New ionic compounds containing an alkaloidal cation and a steroidal anion have been isolated by reverse-phase liquid chromatography from the extracts of the starfish Lethasterias nanimensis chelifera. Their structures have been elucidated by NMR and mass spectroscopy as 1-methyl-6,7-dihydroxy-1,2,3,4-tetrahydroisoquinolinium salts of 3-O-sulfoasterone 1, 3-O-sulfoisoasterone 2 and 3-O-sulfothornasterol A 3. In addition, the alkaloid 1-methyl-1,2,3,4-tetrahydro-beta-carboline-3-carboxylic acid (MTCA) 4 was found in this starfish. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：1935 / 1937

页数：3

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