Direct coupling reaction between alcohols and allyltrimethylsilane catalyzed by phosphomolybdic acid

被引：14

作者：

Kadam, Santosh T. ^{[1
]}

Lee, Hanbin ^{[1
]}

Kim, Sung Soo ^{[1
]}

机构：

[1] Inha Univ, Dept Chem, Inchon 402751, South Korea

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2010年 / 24卷 / 02期

关键词：

allylation; alcohols; allyltrimethylsilane; PMA; EFFICIENT CATALYST; BENZYLIC ALCOHOLS; ALLYLATION; KETONES; CYANOSILYLATION;

D O I：

10.1002/aoc.1527

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Phosphomolybdic acid (PMA) is a simple and efficient catalyst for direct coupling reaction of alcohols with allyltrimethylsilane. Direct nucleophilic allylation of alcohol with allyltrimethylsilane proceeds in considerably good yield in the presence of catalytic amount of (0.5 mol %) PMA at room temperature. Copyright (C) 2009 John Wiley & Sons, Ltd.

引用

页码：67 / 70

页数：4

共 29 条

[1] REDUCTIVE ALKYLATION ARYLATION OF ARYLCARBINOLS AND KETONES WITH ORGANO-SILICON COMPOUNDS
CELLA, JA
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (11) : 2125 - 2130
[2] Bismuth(III) chloride-catalyzed direct deoxygenative allylation of substituted benzylic alcohols with allyltrimethylsilane
De, SK
Gibbs, RA
[J]. TETRAHEDRON LETTERS, 2005, 46 (48) : 8345 - 8350
[3] Firouzabadi H, 2003, SYNTHESIS-STUTTGART, P408
[4] Solvent-free cyanosilylation of aldehydes catalyzed by SMI2
George, Soney C.
Kim, Sung Soo
Kadam, Santosh T.
[J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2007, 21 (11) : 994 - 998
[5] CATALYSIS BY HETEROGENEOUS SUPPORTED HETEROPOLY ACID
IZUMI, Y
HASEBE, R
URABE, K
[J]. JOURNAL OF CATALYSIS, 1983, 84 (02) : 402 - 409
[6] Iron trichloride mediated allylation of lithium alkoxides through an unusual carbon-oxygen bond cleavage
Kabalka, George W.
Yao, Min-Liang
Borella, Scott
Goins, Laura K.
[J]. ORGANOMETALLICS, 2007, 26 (17) : 4112 - 4114
[7] Kadam ST, 2008, B KOREAN CHEM SOC, V29, P1320
[8] N-Iodosuccinimide (NIS) a novel and effective catalyst for the cyanosilylation of aldehydes under mild reaction conditions
Kadam, Santosh T.
Kim, Sung Soo
[J]. CATALYSIS COMMUNICATIONS, 2008, 9 (06) : 1342 - 1345
[9] Kadam ST, 2009, B KOREAN CHEM SOC, V30, P1071
[10] Bis(fluorosulfuryl)imide: A Bronsted acid catalyst for the coupling of allylic and benzylic alcohols with allyltrimethylsilane
Kaur, G
Kaushik, M
Trehan, S
[J]. TETRAHEDRON LETTERS, 1997, 38 (14) : 2521 - 2524

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