Co-solvent exfoliation and suspension of hexagonal boron nitride

被引：109

作者：

Marsh, K. L. ^{[1
,2
]}

Souliman, M. ^{[1
,2
]}

Kaner, R. B. ^{[1
,2
,3
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

[2] Univ Calif Los Angeles, Calif NanoSyst Inst, Los Angeles, CA 90095 USA

[3] Univ Calif Los Angeles, Dept Mat Sci & Engn, Los Angeles, CA 90095 USA

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 01期

关键词：

CHEMICAL-VAPOR-DEPOSITION; LAYERED MATERIALS; LIQUID-PHASE; NANOSHEETS; GRAPHITE; GRAPHENE; CARBON; FOIL;

D O I：

10.1039/c4cc07324j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple method is presented for exfoliating and suspending hexagonal boron nitride using a co-solvent approach. A 60 w/w% concentration of tert-butanol in water is very effective at exfoliating boron nitride especially when compared to the individual components alone as indicated by UV-vis and transmission electron microscopy. Molecular weight and surface tension are found to play inverse roles in the exfoliation.

引用

页码：187 / 190

页数：4

共 23 条

[1]

[Anonymous], 2003, HANDBOOK OF CHEMISTR, P6

[2] Large-scale exfoliation of hexagonal boron nitride nanosheets in liquid phase [J].

Cao, Li ;

Emami, Sadra ;

Lafdi, Khalid .

MATERIALS EXPRESS, 2014, 4 (02) :165-171

[3] Shear induced formation of carbon and boron nitride nano-scrolls [J].

Chen, Xianjue ;

Boulos, Ramiz A. ;

Dobson, John F. ;

Raston, Colin L. .

NANOSCALE, 2013, 5 (02) :498-502

[4] Vortex fluidic exfoliation of graphite and boron nitride [J].

Chen, Xianjue ;

Dobson, John F. ;

Raston, Colin L. .

CHEMICAL COMMUNICATIONS, 2012, 48 (31) :3703-3705

[5] Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials [J].

Coleman, Jonathan N. ;

Lotya, Mustafa ;

O'Neill, Arlene ;

Bergin, Shane D. ;

King, Paul J. ;

Khan, Umar ;

Young, Karen ;

Gaucher, Alexandre ;

De, Sukanta ;

Smith, Ronan J. ;

Shvets, Igor V. ;

Arora, Sunil K. ;

Stanton, George ;

Kim, Hye-Young ;

Lee, Kangho ;

Kim, Gyu Tae ;

Duesberg, Georg S. ;

Hallam, Toby ;

Boland, John J. ;

Wang, Jing Jing ;

Donegan, John F. ;

Grunlan, Jaime C. ;

Moriarty, Gregory ;

Shmeliov, Aleksey ;

Nicholls, Rebecca J. ;

Perkins, James M. ;

Grieveson, Eleanor M. ;

Theuwissen, Koenraad ;

McComb, David W. ;

Nellist, Peter D. ;

Nicolosi, Valeria .

SCIENCE, 2011, 331 (6017) :568-571

[6] One-Step Exfoliation and Fluorination of Boron Nitride Nanosheets and a Study of Their Magnetic Properties [J].

Du, Miao ;

Li, Xianlei ;

Wang, Aizhu ;

Wu, Yongzhong ;

Hao, Xiaopeng ;

Zhao, Mingwen .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (14) :3645-3649

[7]

GLINSKI J, 1995, J CHEM PHYS, V102, P2113, DOI 10.1063/1.468733

[8] A rational design of cosolvent exfoliation of layered materials by directly probing liquid-solid interaction [J].

Halim, Udayabagya ;

Zheng, Chu Ran ;

Chen, Yu ;

Lin, Zhaoyang ;

Jiang, Shan ;

Cheng, Rui ;

Huang, Yu ;

Duan, Xiangfeng .

NATURE COMMUNICATIONS, 2013, 4

[9] High-yield production of graphene by liquid-phase exfoliation of graphite [J].

Hernandez, Yenny ;

Nicolosi, Valeria ;

Lotya, Mustafa ;

Blighe, Fiona M. ;

Sun, Zhenyu ;

De, Sukanta ;

McGovern, I. T. ;

Holland, Brendan ;

Byrne, Michele ;

Gun'ko, Yurii K. ;

Boland, John J. ;

Niraj, Peter ;

Duesberg, Georg ;

Krishnamurthy, Satheesh ;

Goodhue, Robbie ;

Hutchison, John ;

Scardaci, Vittorio ;

Ferrari, Andrea C. ;

Coleman, Jonathan N. .

NATURE NANOTECHNOLOGY, 2008, 3 (09) :563-568

[10] Graphite and Hexagonal Boron-Nitride have the Same Interlayer Distance. Why? [J].

Hod, Oded .

JOURNAL OF CHEMICAL THEORY AND COMPUTATION, 2012, 8 (04) :1360-1369

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