Kinetic aspects of RAFT polymerization

被引：17
|
作者：
Vana, Philipp [1 ]
机构：
[1] Univ Gottingen, Inst Phys Chem, D-37077 Gottingen, Germany
来源：
MACROMOLECULAR SYMPOSIA | 2007年 / 248卷
关键词：
kinetics (polym.); laser-induced polymers; living polymerization; mass spectrometry; reversible addition fragmentation chain transfer (RAFT);
D O I：
10.1002/masy.200750208
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
In this short review, selected experimental approaches for probing the mechanism and kinetics of RAFT polymerization are highlighted. Methods for studying RAFT polymerization via varying reaction conditions, such as pressure, temperature, and solution properties, are reviewed. A technique for the measurement of the RAFT specific addition and fragmentation reaction rates via combination of pulsed-laser-initiated RAFT polymerization and mu s-time-resolved electron spin resonance (ESR) spectroscopy is detailed. Mechanistic investigations using mass spectrometry are exemplified on dithiobenzoic-acid-mediated methyl methacrylate polymerization.
引用
收藏
页码：71 / 81
页数：11
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