Surface modified NiOx as an efficient hole transport layer in inverted perovskite solar cells

被引：4

作者：

Yang, Yan ^{[1
,2
]}

Chen, Jieda ^{[1
,2
]}

Li, Chengyuan ^{[1
]}

Zhang, Wei ^{[2
,3
]}

Zhang, Shan-Ting ^{[2
]}

Li, Dongdong ^{[2
]}

Zhang, Jiafan ^{[2
]}

Ding, Yi'an ^{[2
]}

Lu, Linfeng ^{[2
]}

Song, Ye ^{[1
]}

机构：

[1] Nanjing Univ Sci & Technol, Key Lab Soft Chem & Funct Mat, Educ Minist, Nanjing 210094, Peoples R China

[2] Chinese Acad Sci, Interdisciplinary Res Ctr, Shanghai Adv Res Inst, 99 Haike Rd,Zhangjiang Hitech Pk, Shanghai 201210, Peoples R China

[3] Nanjing Univ Aeronaut & Astronaut, Coll Sci, Jiangsu Key Lab Mat & Technol Energy Convers, Nanjing 210016, Peoples R China

来源：

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS | 2022年 / 33卷 / 23期

基金：

上海市自然科学基金;

关键词：

OXIDE THIN-FILMS; NICKEL-OXIDE; DEFECT PASSIVATION; HIGHLY EFFICIENT; PERFORMANCE; TEMPERATURE; HYSTERESIS; POTASSIUM; LENGTHS; STATES;

D O I：

10.1007/s10854-022-08704-w

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

Hole transporting materials play a vital role in improving the performance of perovskite solar cells (PSCs). In this work, different concentrations of poly[bis(4-phenyl)(2, 4, 6-trimethylphenyl)amine] (PTAA) are used to modify the surface of sputtered nickel oxide (NiOx) as hole transport layer (HTL) in inverted PSCs. After the introduction of PTAA, the roughness of the sputtered NiOx films decreases, while the crystallinity of the perovskite layer increases. The carrier transport across the interface between the sputtered NiOx film and the perovskite layer is significantly improved. A power conversion efficiency of 18.5% is achieved based on PTAA-modified sputtered NiOx, exhibiting a 15.2% improvement compared to its pristine counterpart.

引用

页码：18522 / 18532

页数：11

共 55 条

[1] Thermal oxidation of sputtered nickel nano-film as hole transport layer for high performance perovskite solar cells [J].

Aboulsaad, Mustafa ;

El Tahan, Ayman ;

Soliman, Moataz ;

El-Sheikh, Said ;

Ebrahim, Shaker .

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2019, 30 (22) :19792-19803

[2] Electron-Beam-Evaporated Nickel Oxide Hole Transport Layers for Perovskite-Based Photovoltaics [J].

Abzieher, Tobias ;

Moghadamzadeh, Somayeh ;

Schackmar, Fabian ;

Eggers, Helge ;

Sutterlueti, Florian ;

Farooq, Amjad ;

Kojda, Danny ;

Habicht, Klaus ;

Schmager, Raphael ;

Mertens, Adrian ;

Azmi, Raheleh ;

Klohr, Lukas ;

Schwenzer, Jonas A. ;

Hetterich, Michael ;

Lemmer, Uli ;

Richards, Bryce S. ;

Powalla, Michael ;

Paetzold, Ulrich W. .

ADVANCED ENERGY MATERIALS, 2019, 9 (12)

[3] Influence of substrate temperature on electrical and optical properties of p-type semitransparent conductive nickel oxide thin films deposited by radio frequency sputtering [J].

Ai, Lei ;

Fang, Guojia ;

Yuan, Longyan ;

Liu, Nishuang ;

Wang, Mingjun ;

Li, Chun ;

Zhang, Qilin ;

Li, Jun ;

Zhao, Xingzhong .

APPLIED SURFACE SCIENCE, 2008, 254 (08) :2401-2405

[4] Potassium iodide reduces the stability of triple-cation perovskite solar cells [J].

Alanazi, Tarek, I ;

Game, Onkar S. ;

Smith, Joel A. ;

Kilbride, Rachel C. ;

Greenland, Claire ;

Jayaprakash, Rahul ;

Georgiou, Kyriacos ;

Terrill, Nicholas J. ;

Lidzey, David G. .

RSC ADVANCES, 2020, 10 (66) :40341-40350

[5] Ionic dipolar switching hinders charge collection in perovskite solar cells with normal and inverted hysteresis [J].

Almora, Osbel ;

Lopez-Varo, Pilar ;

Cho, Kyung Taek ;

Aghazada, Sadig ;

Meng, Wei ;

Hou, Yi ;

Echeverria-Arrondo, Carlos ;

Zimmermann, Iwan ;

Matt, Gebhard J. ;

Jimenez-Tejada, Juan A. ;

Brabec, Christoph J. ;

Nazeeruddin, Mohammad Khaja ;

Garcia-Belmonte, Germa .

SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2019, 195 :291-298

[6] Discerning recombination mechanisms and ideality factors through impedance analysis of high-efficiency perovskite solar cells [J].

Almora, Osbel ;

Cho, Kyung Taek ;

Aghazada, Sadig ;

Zimmermann, Iwan ;

Matt, Gebhard J. ;

Brabec, Christoph J. ;

Nazeeruddin, Mohammad Khaja ;

Garcia-Belmonte, Germa .

NANO ENERGY, 2018, 48 :63-72

[7]

[Anonymous], SIM PROGR SCAPS 1D T

[8] Room-Temperature-Sputtered Nanocrystalline Nickel Oxide as Hole Transport Layer for p-i-n Perovskite Solar Cells [J].

Aydin, Erkan ;

Troughton, Joel ;

De Bastiani, Michele ;

Ugur, Esma ;

Sajjad, Muhammad ;

Alzahrani, Areej ;

Neophytou, Marios ;

Schwingenschlogl, Udo ;

Laquai, Frederic ;

Baran, Derya ;

De Wolf, Stefaan .

ACS APPLIED ENERGY MATERIALS, 2018, 1 (11) :6227-6233

[9] Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3) PbI3 for solid-state sensitised solar cell applications [J].

Baikie, Tom ;

Fang, Yanan ;

Kadro, Jeannette M. ;

Schreyer, Martin ;

Wei, Fengxia ;

Mhaisalkar, Subodh G. ;

Graetzel, Michael ;

White, Tim J. .

JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (18) :5628-5641

[10] Controllable Self-Induced Passivation of Hybrid Lead Iodide Perovskites toward High Performance Solar Cells [J].

Chen, Qi ;

Zhou, Huanping ;

Song, Tze-Bin ;

Luo, Song ;

Hong, Ziruo ;

Duan, Hsin-Sheng ;

Dou, Letian ;

Liu, Yongsheng ;

Yang, Yang .

NANO LETTERS, 2014, 14 (07) :4158-4163

← 1 2 3 4 5 6 →