NH3-Selective Catalytic Reduction of NOx to N2 over Ceria Supported WOx Based Catalysts: Influence of Tungsten Content

被引：7
作者：
El Arrouji, Imane [1 ,2 ]
Chen, Cuirong [2 ]
Toyir, Jamil [3 ]
Larabi, Cherif [2 ]
Szeto, Kai C. [2 ]
de Mallmann, Aimery [2 ]
Taoufik, Mostafa [2 ]
Oulmekki, Abdallah [1 ]
机构：
[1] Univ Sidi Mohammed Ben Abdellah, Fac Sci & Tech Fes, Lab Proc Mat & Environm LPME, BP 2202, Fes, Morocco
[2] Univ Lyon 1, Inst Chim Lyon, CPE Lyon CNRS, UMR 5265,C2P2,LCOMS, 43 Bd 11 Novembre 1918, F-69616 Villeurbanne, France
[3] Univ Sidi Mohammed Ben Abdellah, Fac Polydisciplinaire FP Taza, Lab Proc, BP 1223, Taza, Morocco
来源：
CATALYSTS | 2021年 / 11卷 / 08期
关键词：
DeNO(x); 12-tungstophosphoric acid; ceria; tungsten monomeric; CEO2; H3PW12O40; PERFORMANCE; COMBUSTOR; MECHANISM; NH3-SCR; DRIFT; SCR;
D O I：
10.3390/catal11080950
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A series of HPW/CeO2 catalysts generated from 12-tungstophosphoric acid, H3PW12O40 (HPW), supported on ceria and presenting different tungsten loadings (2, 4.5, 9, 16, and 40 wt% W) were prepared and characterized by N-2 physisorption, XRD, IR, Raman, and UV-Vis. The different characterization techniques suggested that low loading of tungsten resulted in mainly isolated sites, while high tungsten loading produced polymeric or tungsten clusters. Those materials exhibited high activity in NH3-SCR of NOx into N-2. Moreover, the series of experiments indicated that low loading in tungsten (2% HPW/CeO2) displayed the highest activity with a remarkable N-2 selectivity (99%) at medium-high temperature (300-515 degrees C), owing to the high amount of monomeric tungstate coverage on the catalyst surface.
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页数：12
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