A novel three dimensional 3d-4f heterometallic coordination framework with 2, 2′-bipyridine-3-carboxylate and oxalate ligands

被引：24

作者：

Tang, Yun-Zhi ^{[1
]}

Wen, He-Rui ^{[1
]}

Cao, Zan ^{[1
]}

Wang, Xiao-Wei ^{[1
]}

Huang, Shuai ^{[1
]}

Yu, Chang-Lin ^{[1
]}

机构：

[1] Jiangxi Univ Sci & Technol, Sch Mat & Chem Engn, Ganzhou 341000, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2010年 / 13卷 / 08期

关键词：

Heterometallic polymer; Hydrothermal synthesis; Neodymium complex; Copper complex; COMPLEXES; HHFAC; GD;

D O I：

10.1016/j.inoche.2010.04.027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 3D heterometallic polymeric complex 1 {[Nd2Cu2(L)(2)(OXA)(4)center dot 2(2H(2)O)]center dot 2(3H(2)O)}(n) (HL = 2, 2'-bipyridine-3-carboxyic acid, OXA = oxalate) was obtained from hydrothermal reaction of Nd2O3, Cu(ClO4)(2), HL and oxalic acid in the presence of ethanol and water. X-ray single crystal diffraction investigation of the polymeric complexes {[Nd2Cu2(L)(2)(OXA)(4)center dot 2(2H(2)O)]center dot 2(3H(2)O)}(n) exhibits an interesting and novel topological structure. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：924 / 928

页数：5

共 22 条

[1] CHEN W, 2003, J AM CHEM SOC, V9266, P125
[2] DENG H, 1991, J AM CHEM SOC, V8538, P113
[3] DENG H, 1996, INORG CHEM, V3891, P35
[4] HE Z, 2003, INORG CHEM, V2206, P42
[5] IGARASHI NS, 2000, INORG CHEM, V2509, P39
[6] KELLY KR, 2008, CRYSTENGCOMM, V68, P10
[7] KELLY MR, 2008, CRYSTENGCOMM, V1018, P10
[8] Nature of copper(II)-lanthanide(III) magnetic interactions and generation of a large magnetic moment with magnetic anisotropy of 3d-4f cyclic cylindrical tetranuclear complexes [CuIILLnIII(hfaC)2]2, (H3L=1-(2-hydroxybenzamido)-2-(2-hydroxy-3-methoxybenzylideneamino)ethane and Hhfac = hexafluoroacetylacetone, LnIII = Eu, Gd, Tb, Dy)
Kido, T
Ikuta, Y
Sunatsuki, Y
Ogawa, Y
Matsumoto, N
[J]. INORGANIC CHEMISTRY, 2003, 42 (02) : 398 - 408
[9] LIANG YC, 2000, ANGEW CHEM INT EDIT, V3304, P39
[10] LIANG YC, 2002, INORG CHEM COMMUN, V366, P5

← 1 2 3 →