Recent advances in the synthesis of indole embedded heterocycles with 3-diazoindolin-2-imines

被引：34
|
作者：
Suleman, Muhammad [1 ]
Lu, Ping [1 ]
Wang, Yanguang [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2021年 / 8卷 / 09期
关键词：
RH-CATALYZED TRANSANNULATION; ELECTRON-RICH ARENES; RHODIUM; CYCLOADDITION; REACTIVITY; ACCESS; 3-ARYL-2-AMINOINDOLES; 1,2,3-TRIAZOLES; SULFONYLAZIDES; CARBENES;
D O I：
10.1039/d0qo01515f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Indole embedded alpha-diazo amidines (i.e. 3-diazoindolin-2-imines) are important additions to the cyclic diazo compound family. The ease of their preparation, typical reactivity as diazo compounds, successful generation of Rh, Cu, Pd, Co and Au carbenes in situ and their numerous transformations make them an imperative part for modern synthesis of indole embedded heterocycles. Chemistry and synthetic applications of these valuable cyclic diazo compounds are reviewed here.
引用
收藏
页码：2059 / 2078
页数：20
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