Study of Acidic (Tetracaprolactam) Dodecamolybdosilicate of the Composition (C6H11NO)4.5De4[SiDeD3/412O40]

被引：1

作者：

Stepnova, A. F. ^{[1
]}

Kaziev, G. Z. ^{[1
]}

Dorovatovskii, P. V. ^{[2
]}

Zubavichus, Ya. V. ^{[2
]}

Holguin Quinones, Saul ^{[3
]}

Nguen Van Bang ^{[1
]}

Khrustalev, V. N. ^{[4
]}

机构：

[1] Moscow State Pedag Univ, Moscow, Russia

[2] Natl Res Ctr Kurchatov Inst, Moscow, Russia

[3] Univ Autonoma Metropolitana Azcapotzalco, Mexico City, DF, Mexico

[4] Russian Univ Peoples Friendship, Moscow, Russia

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 2018年 / 59卷 / 03期

关键词：

synthesis; heteropolycompound; polyoxometallates; caprolactam; structural analysis;

D O I：

10.1134/S0022476618030174

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New caprolactam dodecamolybdosilicate of the composition (C6H11NO)(4.5)De(4)[SiDeD 3/4 O-12(40)] (I) is synthesized. Chemical and crystallographic analyses, NMR and IR spectroscopic studies are performed. Compound I is found to crystallize in the monoclinic system with the space group P2(1)/n. Unit cell parameters are: a = 19.945(4) , b = 13.340(3) , c = 28.110(6) , beta = 110.75(3)A degrees, rho(calc) = 2.232 g/cm(3), De = 2350.63, Z = 4, V = 6994(3) (3).

引用

页码：627 / 634

页数：8

共 19 条

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