Highly Efficient Organic Light-Emitting Diode Using A Low Refractive Index Electron Transport Layer

被引:53
作者
Salehi, Amin [1 ]
Ho, Szuheng [2 ]
Chen, Ying [3 ]
Peng, Cheng [2 ]
Yersin, Hartmut [4 ]
So, Franky [3 ]
机构
[1] North Carolina State Univ, Dept Phys, Raleigh, NC 27695 USA
[2] Univ Florida, Dept Mat Sci & Engn, Gainesville, FL 32611 USA
[3] North Carolina State Univ, Dept Mat Sci & Engn, Raleigh, NC 27695 USA
[4] Univ Regensburg, Inst Phys Chem, D-93040 Regensburg, Germany
关键词
electron transport layers; low refractive indexes; organic light emitting diodes; thermally activated delayed florescence; OPERATIONAL STABILITY; HOST MATERIALS; SKY-BLUE; DEVICES; OLEDS; GREEN; FLUORESCENCE; RED;
D O I
10.1002/adom.201700197
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A low refractive index electron transport layer (ETL) can be very effective in enhancing the out-coupling efficiency of an organic light-emitting diode (OLED). However, most organic films show a refractive index close to 1.8. In this work, it has been discovered that tris-[3-(3-pyridyl) mesityl] borane (3TPYMB) has a low refractive index of 1.65 (at 550 nm), which is the lowest refractive index ETL among the commonly used ETLs up to date. Using 3TPYMB as an ETL, a solution processed OLED is demonstrated with nearly a 76% enhancement in external quantum efficiency (EQE). Optical simulation results of this study show that 59% of the enhancement comes from the low refractive index 3TPYMB, and the remaining 17% from the change in charge balance due to the 3TPYMB ETL in the OLED devices.
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页数:7
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