Synthesis and characterization of diiron ethane-1,2-dithiolate complexes with tricyclohexylphosphine, methyl diphenylphosphinite, or tris(2-thienyl)phosphine coligands

被引：3
作者：
Yan, Lin [1 ]
Li, Ao [2 ]
Xiao, Qi-Min [2 ]
Liu, Xu-Feng [1 ]
Li, Yu-Long [2 ]
Jiang, Zhong-Qing [3 ]
Wu, Hong-Ke [4 ]
机构：
[1] Ningbo Univ Technol, Sch Mat & Chem Engn, Ningbo 315211, Zhejiang, Peoples R China
[2] Sichuan Univ Sci & Engn, Coll Chem & Environm Engn, Zigong 643000, Peoples R China
[3] Zhejiang Sci Tech Univ, Minist Educ, Dept Phys, Key Lab ATMMT, Hangzhou 310018, Zhejiang, Peoples R China
[4] Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Zhejiang, Peoples R China
来源：
TRANSITION METAL CHEMISTRY | 2019年 / 44卷 / 05期
基金：
中国国家自然科学基金;
关键词：
FE-ONLY HYDROGENASE; ACTIVE-SITE; IRON HYDROGENASE; ETHANEDITHIOLATE COMPLEXES; ELECTROCHEMICAL PROPERTIES; MODELS; COORDINATION; EVOLUTION; DINUCLEAR; ANALOGS;
D O I：
10.1007/s11243-019-00339-x
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We have prepared three diiron ethane-1,2-dithiolate complexes [Fe-2(CO)(5)L(mu-SCH2CH2S)] [L = P(C6H11)(3), 2; Ph2POCH3, 3; P(2-C4H3S)(3), 4] by CO exchange of the starting complex [Fe-2(CO)(6)(mu-SCH2CH2S)] (1) with the corresponding phosphine ligands tricyclohexylphosphine, methyl diphenylphosphinite, or tris(2-thienyl)phosphine in the presence of Me3NO as an oxidant for CO. The complexes have been characterized by elemental analysis, spectroscopy, and single-crystal X-ray diffraction analysis.
引用
收藏
页码：483 / 489
页数：7
相关论文
共 44 条
  • [1] [FeFe]-Hydrogenase H-Cluster Mimics with Various -S(CH2)nS- Linker Lengths (n=2-8): A Systematic Study
    Abul-Futouh, Hassan
    Almazahreh, Laith R.
    Harb, Mohammad Kamal
    Goerls, Helmar
    El-khateeb, Mohammad
    Weigand, Wolfgang
    [J]. INORGANIC CHEMISTRY, 2017, 56 (17) : 10437 - 10451
  • [2] [Anonymous], 2007, VERSION 20097 0 BRUK
  • [3] Biomimetic assembly and activation of [FeFe]-hydrogenases
    Berggren, G.
    Adamska, A.
    Lambertz, C.
    Simmons, T. R.
    Esselborn, J.
    Atta, M.
    Gambarelli, S.
    Mouesca, J. -M.
    Reijerse, E.
    Lubitz, W.
    Happe, T.
    Artero, V.
    Fontecave, M.
    [J]. NATURE, 2013, 499 (7456) : 66 - +
  • [4] Bioinorganic chemistry - Hydrogenase sophistication
    Cammack, R
    [J]. NATURE, 1999, 397 (6716) : 214 - 215
  • [5] N-heterocyclic carbene ligands as cyanide mimics in diiron models of the all-iron hydrogenase active site
    Capon, JF
    El Hassnaoui, S
    Gloaguen, F
    Schollhammer, P
    Talarmin, J
    [J]. ORGANOMETALLICS, 2005, 24 (09) : 2020 - 2022
  • [6] Synthesis and characterization of five diiron ethanedithiolate complexes with acetate group and phosphine ligands
    Chen, Fei-Yan
    He, Jiao
    Mu, Chao
    Liu, Xu-Feng
    Li, Yu -Long
    Jiang, Zhong-Qing
    Wu, Hong-Ke
    [J]. POLYHEDRON, 2019, 160 : 74 - 82
  • [7] Synthesis and characterization of diiron ethanedithiolate complexes with monosubstituted phosphine ligands
    Chen, Xiao-Qin
    Liu, Xu-Feng
    Jiang, Zhong-Qing
    Zhang, Ying-Xin
    Li, Xie
    Tian, Xiao-Ning
    Liu, Xing-Hai
    [J]. JOURNAL OF COORDINATION CHEMISTRY, 2016, 69 (09) : 1439 - 1446
  • [8] Electrocatalysis of hydrogen production by active site analogues of the iron hydrogenase enzyme: structure/function relationships
    Chong, DS
    Georgakaki, IP
    Mejia-Rodriguez, R
    Samabria-Chinchilla, J
    Soriaga, MP
    Darensbourg, MY
    [J]. DALTON TRANSACTIONS, 2003, (21) : 4158 - 4163
  • [9] FTIR characterization of the active site of the Fe-hydrogenase from Desulfovibrio desulfuricans
    De Lacey, AL
    Stadler, C
    Cavazza, C
    Hatchikian, EC
    Fernandez, VM
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (45) : 11232 - 11233
  • [10] OLEX2: a complete structure solution, refinement and analysis program
    Dolomanov, Oleg V.
    Bourhis, Luc J.
    Gildea, Richard J.
    Howard, Judith A. K.
    Puschmann, Horst
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 : 339 - 341
12345