Ultralow-fluence single-shot optical crystalline-to-amorphous phase transition in Ge-Sb-Te nanoparticles

被引:7
作者
Casarin, Barbara [1 ]
Caretta, Antonio [2 ]
Chen, Bin [3 ]
Kooi, Bart J. [3 ]
Ciprian, Roberta [2 ]
Parmigiani, Fulvio [1 ,2 ,4 ]
Malvestuto, Marco [2 ]
机构
[1] Univ Trieste, Via A Valerio 2, I-34127 Trieste, Italy
[2] Elettra Sincrotrone Trieste SCpA, Str Statale 14 Km 163-5,AREA Sci Pk, I-34149 Trieste, Italy
[3] Univ Groningen, Zernike Inst Adv Mat, NL-9747 AG Groningen, Netherlands
[4] Univ Cologne, Int Fac, D-50937 Cologne, Germany
关键词
STRUCTURAL TRANSITIONS; GE2SB2TE5; MEMORY; FILMS; NONVOLATILE; DISORDER; NANOWIRE; MEDIA;
D O I
10.1039/c8nr04350g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Here we demonstrate that the 0-dimensional confinement of Ge2Sb2Te5 results in a drastic reduction of the minimum critical fluence required for optical-induced amorphization when compared to the thin-film cases. We show that by using single-shot laser pulses, the investigated nanoparticles display a crystalline-to-amorphous transition, satisfying a mandatory requirement of a bit-memory element. These unprecedented results open a viable route to boost energy efficient phase-change processes.
引用
收藏
页码:16574 / 16580
页数:7
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[41]   Structural transition and enhanced phase transition properties of Se doped Ge2Sb2Te5 alloys [J].
Vinod, E. M. ;
Ramesh, K. ;
Sangunni, K. S. .
SCIENTIFIC REPORTS, 2015, 5
[42]   Signatures of Ge2Sb2Te5 film at structural transitions [J].
Vinod, E. M. ;
Naik, Ramakanta ;
Ganesan, R. ;
Sangunni, K. S. .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2012, 358 (21) :2927-2930
[43]  
Waldecker L, 2015, NAT MATER, V14, P991, DOI [10.1038/NMAT4359, 10.1038/nmat4359]
[44]   Genome engineering Escherichia coli for L-DOPA overproduction from glucose [J].
Wei, Tao ;
Cheng, Bi-Yan ;
Liu, Jian-Zhong .
SCIENTIFIC REPORTS, 2016, 6
[45]   Phase-change materials for rewriteable data storage [J].
Wuttig, Matthias ;
Yamada, Noboru .
NATURE MATERIALS, 2007, 6 (11) :824-832
[46]   Low-Power Switching of Phase-Change Materials with Carbon Nanotube Electrodes [J].
Xiong, Feng ;
Liao, Albert D. ;
Estrada, David ;
Pop, Eric .
SCIENCE, 2011, 332 (6029) :568-570
[47]   RAPID-PHASE TRANSITIONS OF GETE-SB2 TE3 PSEUDOBINARY AMORPHOUS THIN-FILMS FOR AN OPTICAL DISK MEMORY [J].
YAMADA, N ;
OHNO, E ;
NISHIUCHI, K ;
AKAHIRA, N ;
TAKAO, M .
JOURNAL OF APPLIED PHYSICS, 1991, 69 (05) :2849-2856
[48]   Generation of phase-change Ge-Sb-Te nanoparticles by pulsed laser ablation [J].
Yoon, HR ;
Jo, W ;
Lee, EH ;
Lee, JH ;
Kim, M ;
Lee, KY ;
Khang, Y .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2005, 351 (43-45) :3430-3434
[49]   Specific Heat of (GeTe)x(Sb2Te3)1-x Phase-Change Materials: The Impact of Disorder and Anharmonicity [J].
Zalden, Peter ;
Siegert, Karl Simon ;
Rols, Stephane ;
Fischer, Henry E. ;
Schlich, Franziska ;
Hu, Te ;
Wuttig, Matthias .
CHEMISTRY OF MATERIALS, 2014, 26 (07) :2307-2312
[50]   Modeling of the Melting Point, Debye Temperature, Thermal Expansion Coefficient, and the Specific Heat of Nanostructured Materials [J].
Zhu, Y. F. ;
Lian, J. S. ;
Jiang, Q. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (39) :16896-16900