Ultralow-fluence single-shot optical crystalline-to-amorphous phase transition in Ge-Sb-Te nanoparticles

被引:7
作者
Casarin, Barbara [1 ]
Caretta, Antonio [2 ]
Chen, Bin [3 ]
Kooi, Bart J. [3 ]
Ciprian, Roberta [2 ]
Parmigiani, Fulvio [1 ,2 ,4 ]
Malvestuto, Marco [2 ]
机构
[1] Univ Trieste, Via A Valerio 2, I-34127 Trieste, Italy
[2] Elettra Sincrotrone Trieste SCpA, Str Statale 14 Km 163-5,AREA Sci Pk, I-34149 Trieste, Italy
[3] Univ Groningen, Zernike Inst Adv Mat, NL-9747 AG Groningen, Netherlands
[4] Univ Cologne, Int Fac, D-50937 Cologne, Germany
关键词
STRUCTURAL TRANSITIONS; GE2SB2TE5; MEMORY; FILMS; NONVOLATILE; DISORDER; NANOWIRE; MEDIA;
D O I
10.1039/c8nr04350g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Here we demonstrate that the 0-dimensional confinement of Ge2Sb2Te5 results in a drastic reduction of the minimum critical fluence required for optical-induced amorphization when compared to the thin-film cases. We show that by using single-shot laser pulses, the investigated nanoparticles display a crystalline-to-amorphous transition, satisfying a mandatory requirement of a bit-memory element. These unprecedented results open a viable route to boost energy efficient phase-change processes.
引用
收藏
页码:16574 / 16580
页数:7
相关论文
共 50 条
[1]   SMALL PARTICLE MELTING OF PURE METALS [J].
ALLEN, GL ;
BAYLES, RA ;
GILE, WW ;
JESSER, WA .
THIN SOLID FILMS, 1986, 144 (02) :297-308
[2]   SIZE EFFECT ON MELTING TEMPERATURE OF GOLD PARTICLES [J].
BUFFAT, P ;
BOREL, JP .
PHYSICAL REVIEW A, 1976, 13 (06) :2287-2298
[3]   Synthesis and size-dependent crystallization of colloidal germanium telluride nanoparticles [J].
Caldwell, Marissa A. ;
Raoux, Simone ;
Wang, Robert Y. ;
Wong, H. -S. Philip ;
Milliron, Delia J. .
JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (07) :1285-1291
[4]   Crystallization Kinetics of GeSbTe Phase-Change Nanoparticles Resolved by Ultrafast Calorimetry [J].
Chen, Bin ;
ten Brink, Gert H. ;
Palasantzas, George ;
Kooi, Bart J. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2017, 121 (15) :8569-8578
[5]   Synthesis of size- and structure- controlled Ge2Sb2Te5 nanoparticles [J].
Choi, HS ;
Seol, KS ;
Takeuchi, K ;
Fujita, J ;
Ohki, Y .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2005, 44 (10) :7720-7722
[6]   OPTICAL PROPERTIES OF GRANULAR SILVER AND GOLD FILMS [J].
COHEN, RW ;
CODY, GD ;
COUTTS, MD ;
ABELES, B .
PHYSICAL REVIEW B, 1973, 8 (08) :3689-3701
[7]   Binding energy, vapor pressure, and melting point of semiconductor nanoparticles [J].
Farrell, H. H. ;
Van Siclen, C. D. .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 2007, 25 (04) :1441-1447
[8]   Confined Crystals of the Smallest Phase-Change Material [J].
Giusca, Cristina E. ;
Stolojan, Vlad ;
Sloan, Jeremy ;
Boerrnert, Felix ;
Shiozawa, Hidetsugu ;
Sader, Kasim ;
Ruemmeli, Mark H. ;
Buechner, Bernd ;
Silva, S. Ravi P. .
NANO LETTERS, 2013, 13 (09) :4020-4027
[9]   Ultrafast time-resolved electron diffraction revealing the nonthermal dynamics of near-UV photoexcitation-induced amorphization in Ge2Sb2Te5 [J].
Hada, Masaki ;
Oba, Wataru ;
Kuwahara, Masashi ;
Katayama, Ikufumi ;
Saiki, Toshiharu ;
Takeda, Jun ;
Nakamura, Kazutaka G. .
SCIENTIFIC REPORTS, 2015, 5
[10]   Bonding origin of optical contrast in phase-change memory materials [J].
Huang, B. ;
Robertson, J. .
PHYSICAL REVIEW B, 2010, 81 (08)