The isothermal section of the Al-Cr-Si system at 800 °C and the crystal structure of τ2 (Cr3Al9Si)

被引:22
作者
Chen, Hai-Lin [1 ]
Weitzer, F.
Schuster, J. C.
Du, Y.
Xu, Honghui
机构
[1] Cent S Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
[2] Univ Vienna, Innovat Mat Grp, A-1090 Vienna, Austria
基金
奥地利科学基金会;
关键词
intermetallics; scanning electron microscopy (SEM); X-ray diffraction;
D O I
10.1016/j.jallcom.2006.07.038
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The system Al-Cr-Si at 800 degrees C is investigated using XRD and SEM/EDX on equilibrated alloys. Three ternary phases are found: tau(1)-Cr4Al13Si4 (F43m,Cr4Al13Si4-type, a= 1.09270(2)nm),tau(2)-Cr3Al9Si(P6(3)/mmc,Mn3Al9Si-type, a= 0.75346(3)nm,c=0.78393(4)nm)and tau(3)-Cr-4(AI,Si) I I (P-11 Mn4Al11 -type, a= 0.51260(2)nm, b=0.89802(4)nm, c=0.50472(3)nm, alpha=89.775(4)degrees, beta= 100.711(4)degrees and gamma=106.605(3)degrees for Cr27Al63Si10). Extended homogeneity ranges for tau(3) and several solid binary phases into the ternary are observed. The tie-lines between these phases are determined and the isothermal section at 800 degrees C over the entire composition range is presented. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:313 / 318
页数:6
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