Time-dependent non-linear size change of C60-ethylenediamine adduct particles in formation process

被引：9

作者：

Akiyama, Tsuyoshi ^{[1
]}

Ono, Yuji ^{[2
]}

Miyamura, Hiroshi ^{[1
]}

Saito, Jo ^{[1
]}

Kimura, Kento ^{[2
]}

Higashida, Suguru ^{[3
]}

Oku, Takeo ^{[1
]}

机构：

[1] Univ Shiga Prefecture, Sch Engn, Dept Mat Sci, 2500 Hassaka, Hikone, Shiga 5228533, Japan

[2] Univ Shiga Prefecture, Grad Sch Engn, Div Mat Sci, 2500 Hassaka, Hikone, Shiga 5228533, Japan

[3] Osaka Prefecture Univ, Coll Technol, Dept Technol Syst, Environm & Mat Chem Course, 26-12 Saiwai, Neyagawa, Osaka 5728572, Japan

来源：

JOURNAL OF NANOPARTICLE RESEARCH | 2018年 / 20卷 / 09期

关键词：

Fullerene; Amination; Fulleme-diamine adduct particle; Aggregation; Dissociation; Nanoparticle assemblies; PHOTOVOLTAIC APPLICATION; THIN-FILM; FULLERENE; C-60; FABRICATION; MICROPARTICLES; CELLS;

D O I：

10.1007/s11051-018-4353-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition reaction between C-60 and ethylenediamine occurred at room temperature in an ambient condition. C-60-ethylenediamine adduct particles were prepared by mixing toluene solutions of C-60 and ethyelenediamine. Average diameter of the C-60-ethylenediamine adduct particles was changed non-linearly according to the reaction time, which were observed using transmission electron microscopy. Early stage of the reaction, the diameter of the adduct particles was changed from about 250 to about 430 nm. Then, the size of the adduct particles was converged to about 300 nm. During this addition reaction, the crystalline sizes of adduct particles were constant about 2-3 nm, regardless of the sizes of the adduct particles, which were determined by X-ray diffraction measurement.

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页数：6

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