Nucleophilic Phosphinidene Complexes: Access and Applicability

被引：208
作者：
Aktas, Halil [1 ]
Slootweg, J. Chris [1 ]
Lammertsma, Koop [1 ]
机构：
[1] Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 12期
关键词：
carbene homologues; phosphinidene ligands; phosphorus; synthesis design; transition metals; TRANSITION-METAL-COMPLEXES; COORDINATE PHOSPHORUS ATOMS; N-HETEROCYCLIC CARBENES; BOND-FORMING REACTIONS; RAY CRYSTAL-STRUCTURE; C-H ACTIVATION; P-H; AMINOPHOSPHINIDENE COMPLEXES; NEOPENTYLIDENE COMPLEXES; TUNGSTEN COMPLEXES;
D O I：
10.1002/anie.200905689
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Syntheses, properties, and reactivities of nucleophilic phosphinidene complexes [LnM=P-R] are reviewed. Emphasis is placed on the electronic tuning of this emerging class of phosphorus reagents, using different ancillary ligands and coordinatively unsaturated transitionmetal moieties. The difference in applicability of the established stable 18-electron and transient 16-electron phosphinidenes is addressed. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
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收藏
页码：2102 / 2113
页数：12
相关论文
共 130 条
[61]   P-H AND CYCLOPENTADIENYL C-H ACTIVATION EN-ROUTE TO HOMOBINUCLEAR AND HETEROBINUCLEAR ZIRCONOCENE PHOSPHIDE AND PHOSPHINIDENE COMPLEXES [J].
HO, JW ;
HOU, ZM ;
DRAKE, RJ ;
STEPHAN, DW .
ORGANOMETALLICS, 1993, 12 (08) :3145-3157
[62]   SYNTHESIS OF ZIRCONOCENE PHOSPHINIDENES AND PHOSPHIDES VIA P-H ACTIVATION [J].
HO, JW ;
STEPHAN, DW .
ORGANOMETALLICS, 1991, 10 (09) :3001-3003
[63]   SYNTHESIS, STRUCTURE, AND BONDING IN ZIRCONOCENE PRIMARY PHOSPHIDO (PHR-), PHOSPHINIDENE (PR2-), AND PHOSPHIDE (P3-) DERIVATIVES [J].
HO, JW ;
ROUSSEAU, R ;
STEPHAN, DW .
ORGANOMETALLICS, 1994, 13 (05) :1918-1926
[64]   4-DIALKYLAMINOPYRIDINES AS ACYLATION CATALYSTS .4. 4-DIALKYLAMINOPYRIDINES AS HIGHLY ACTIVE ACYLATION CATALYSTS [J].
HOFLE, G ;
STEGLICH, W ;
VORBRUGGEN, H .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1978, 17 (08) :569-&
[65]  
Hofle G., 1978, ANGEW CHEM, V90, P602
[66]   FORMATION AND REACTIVITY OF THE EARLY METAL PHOSPHIDES AND PHOSPHINIDENES CP-ASTERISK-2ZR=PR, CP-ASTERISK-2ZR(PR)2, AND CP-ASTERISK-2ZR(PR)3 [J].
HOU, ZM ;
BREEN, TL ;
STEPHAN, DW .
ORGANOMETALLICS, 1993, 12 (08) :3158-3167
[67]   GENERATION AND REACTIVITY OF THE 1ST-MONONUCLEAR EARLY METAL PHOSPHINIDENE COMPLEX, CP-ASTERISK-2ZR=P(C6H2ME3-2,4,6) [J].
HOU, ZM ;
STEPHAN, DW .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (25) :10088-10089
[68]   Stereoelectronic effects characterizing nucleophilic carbene ligands bound to the Cp*RuCl (Cp* = η5-C5Me5) moiety:: A structural and thermochemical investigation [J].
Huang, JK ;
Schanz, HJ ;
Stevens, ED ;
Nolan, SP .
ORGANOMETALLICS, 1999, 18 (12) :2370-2375
[69]   [BIS(DIISOPROPYLAMINO)PHOSPHINO]TRIMETHYLSILYLCARBENE - A STABLE NUCLEOPHILIC CARBENE [J].
IGAU, A ;
BACEIREDO, A ;
TRINQUIER, G ;
BERTRAND, G .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (05) :621-622
[70]   ANALOGOUS ALPHA,ALPHA'-BIS-CARBENOID TRIPLY BONDED SPECIES - SYNTHESIS OF A STABLE LAMBDA-3-PHOSPHINOCARBENE LAMBDA-5-PHOSPHAACETYLENE [J].
IGAU, A ;
GRUTZMACHER, H ;
BACEIREDO, A ;
BERTRAND, G .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (19) :6463-6466
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