Manganese-Catalyzed Oxophosphorylation Reaction of Carbon-Carbon Double Bonds Using Molecular Oxygen in Air

被引：10
作者：
Yamamoto, Daisuke [1 ]
Ansai, Hiromasa
Hoshino, Junichi
Makino, Kazuishi [1 ]
机构：
[1] Kitasato Univ, Grad Sch Pharmaceut Sci, Lab Organ Chem Drug Dev, Minato Ku, Tokyo 1088641, Japan
来源：
CHEMICAL & PHARMACEUTICAL BULLETIN | 2018年 / 66卷 / 09期
基金：
日本学术振兴会;
关键词：
oxophosphorylation; atmospheric oxygen; manganese catalyst; beta-ketophosphonate; BETA-KETO PHOSPHONATES; DIRECT OXYPHOSPHORYLATION; H-PHOSPHONATES; AEROBIC OXYPHOSPHORYLATION; N-HYDROXYPHTHALIMIDE; CARBOXYLIC-ACIDS; OLEFIN SYNTHESIS; ALKENES; KETOPHOSPHONATES; ALKYNES;
D O I：
10.1248/cpb.c18-00381
中图分类号：
R914 [药物化学];
学科分类号：
100701 ;
摘要：
A novel aerobic manganese-catalyzed oxophosphorylation reaction of carbon-carbon double bonds of styrene derivatives and vinyl ethers using diethyl H-phosphonates was developed. This direct transformation of alkenes to beta-ketophosphonate readily proceeded at room temperature via the direct incorporation of molecular oxygen present in air (open flask).
引用
收藏
页码：873 / 879
页数：7
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