Total synthesis of (±)-Vertine with Z-selective RCM as a key step

被引：19

作者：

Chausset-Boissarie, Laetitia ^{[1
]}

Arvai, Roman ^{[1
]}

Cumming, Graham R. ^{[1
]}

Besnard, Celine ^{[1
]}

Kuendig, E. Peter ^{[1
]}

机构：

[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 34期

基金：

瑞士国家科学基金会;

关键词：

METHOXYMETHYL MOM ETHERS; CROSS-COUPLING REACTIONS; RING-CLOSING METATHESIS; HEIMIA-SALICIFOLIA; LYTHRACEAE ALKALOIDS; ORGANOBORON COMPOUNDS; DEPROTECTION; EFFICIENT; CHEMOTAXONOMY; ALCOHOLS;

D O I：

10.1039/c0cc01885f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A concise total synthesis of the strained pentacyclic alkaloid (+/-)-Vertine has been achieved in eleven steps with the key steps being pelletierine condensation, Suzuki-Miyaura coupling, and ring-closing metathesis.

引用

页码：6264 / 6266

页数：3

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