Catalytic asymmetric alkylation in aqueous micelles

被引：37
|
作者：
Rabeyrin, C [1 ]
Nguefack, C [1 ]
Sinou, D [1 ]
机构：
[1] Univ Lyon 1, CPE Lyon, CNRS, Lab Synth Asymetr, F-69622 Villeurbanne, France
来源：
TETRAHEDRON LETTERS | 2000年 / 41卷 / 39期
关键词：
asymmetric alkylation; palladium; water; surfactants;
D O I：
10.1016/S0040-4039(00)01293-4
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium-catalyzed alkylation of 1,3-diphenyl-2-propenyl acetate with dimethyl malonate occurred in water in the presence of surfactants, using K2CO3 as the base. Enantioselectivities of up to 92% were obtained using chiral atropoisomeric diphosphines. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：7461 / 7464
页数：4
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