Platinum-alkynyl and -alkyne complexes: old systems with new chemical and physical perspectives

被引：69

作者：

Belluco, U

Bertani, R

Michelin, RA

Mozzon, M

机构：

[1] Univ Padua, CNR, Dipartimento Proc Chim Ingn, I-35131 Padua, Italy

[2] Univ Padua, CNR, Ctr Chim & Tecnol Composti Met Organ Elementi Tra, I-35131 Padua, Italy

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 600卷 / 1-2期

关键词：

platinum; alkynes; alkynyls; mono- and polynuclear complexes;

D O I：

10.1016/S0022-328X(00)00089-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The chemistry of alkynyl and alkyne ligands in platinum complexes of different oxidation states is described. The review focuses on the synthetic aspects of mono- and polynuclear compounds and on the reactivity of sigma-alkynyl and pi-alkyne species in different stoichiometric reactions such as insertion, addition of nucleophiles and electrophiles, rearrangements and isomerization processes and also some catalytic additions of heteroatoms (B, Si, S) across the C=C triple bond. The relevant features of polynuclear complexes bearing the C=C group in dendrimers and organometallic polymers are briefly reported. (C) 2000 Elsevier Science S.A. All rights reserved.

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页码：37 / 55

页数：19

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