Novel molybdenum complexes with the 3,6-Di-tert-butylcatecholate ligand

被引：4
作者：
Petrov, P. A. [1 ,2 ]
Afonin, M. Yu. [1 ]
Naumov, D. Yu. [1 ]
Konchenko, S. N. [1 ,2 ]
Piskunov, A. V. [3 ,4 ]
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia
[2] Novosibirsk State Univ, Novosibirsk 630090, Russia
[3] Russian Acad Sci, Razuvaev Inst Organometall Chem, Nizhnii Novgorod, Russia
[4] Lobachevsky State Univ, Nizhnii Novgorod, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2015年 / 41卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
TRANSITION-METAL-COMPLEXES; REVERSIBLE BINDING; ELECTRON-TRANSFER; COORDINATION; OXYGEN; REACTIVITY; CLUSTERS;
D O I：
10.1134/S1070328415010078
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A reaction of the cluster (Et4N)(2)[Mo3S7Br6] with potassium 3,6-di-tert-butyl-o-benzosemiquinolate (KSQ(36)) afforded the mononuclear complexes (Et4N)[Mo(Cat(36))(3)] (I) and (Et4N)[MoO(Cat(36))(2)(HCat(36))] (II) with prismatic and octahedral environments of their central metal atoms, respectively. Complex I was also obtained by a reaction between MoCl5, sodium 3,6-di-tert-butylcatecholate (Na(2)Cat(36)), and Et4NBr. Complexes I and II were characterized by X-ray diffraction and EPR spectroscopy. The structures have been deposited with the Cambridge Structural Database (nos. 1009139 (I), 1009140 (I center dot 1.5THF), and 1009141 (II center dot Et2O)).
引用
收藏
页码：31 / 36
页数：6
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