Novel molybdenum complexes with the 3,6-Di-tert-butylcatecholate ligand

被引：4

作者：

Petrov, P. A. ^{[1
,2
]}

Afonin, M. Yu. ^{[1
]}

Naumov, D. Yu. ^{[1
]}

Konchenko, S. N. ^{[1
,2
]}

Piskunov, A. V. ^{[3
,4
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk, Russia

[2] Novosibirsk State Univ, Novosibirsk 630090, Russia

[3] Russian Acad Sci, Razuvaev Inst Organometall Chem, Nizhnii Novgorod, Russia

[4] Lobachevsky State Univ, Nizhnii Novgorod, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2015年 / 41卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

TRANSITION-METAL-COMPLEXES; REVERSIBLE BINDING; ELECTRON-TRANSFER; COORDINATION; OXYGEN; REACTIVITY; CLUSTERS;

D O I：

10.1134/S1070328415010078

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A reaction of the cluster (Et4N)(2)[Mo3S7Br6] with potassium 3,6-di-tert-butyl-o-benzosemiquinolate (KSQ(36)) afforded the mononuclear complexes (Et4N)[Mo(Cat(36))(3)] (I) and (Et4N)[MoO(Cat(36))(2)(HCat(36))] (II) with prismatic and octahedral environments of their central metal atoms, respectively. Complex I was also obtained by a reaction between MoCl5, sodium 3,6-di-tert-butylcatecholate (Na(2)Cat(36)), and Et4NBr. Complexes I and II were characterized by X-ray diffraction and EPR spectroscopy. The structures have been deposited with the Cambridge Structural Database (nos. 1009139 (I), 1009140 (I center dot 1.5THF), and 1009141 (II center dot Et2O)).

引用

页码：31 / 36

页数：6

共 50 条

[1] Synthesis of titanium(iv) 3,6-di-tert-butylcatecholate complexes
Meshcheryakova, I. N.
Shavyrin, A. S.
Cherkasov, A., V
Piskunov, A., V
RUSSIAN CHEMICAL BULLETIN, 2019, 68 (07) : 1414 - 1423
[2] Yttrium Complexes with 3,6-Bis(tert-Butylcatecholate)
Petrov, P. A.
Samsonenko, D. G.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2017, 43 (08) : 500 - 504
[3] Synthesis, structure, and magnetic properties of the iron(iii) iodide complex with the 3,5-di-tert-butylcatecholate ligand
Yambulatov, D. S.
Nikolaevskii, S. A.
Babeshkin, K. A.
Efimov, N. N.
Voronina, J. K.
Starikova, A. A.
Goloveshkin, A. S.
Kiskin, M. A.
Eremenko, I. L.
RUSSIAN CHEMICAL BULLETIN, 2022, 71 (07) : 1385 - 1393
[4] Structure and Magnetic Properties of Mixed-Ligand Complexes of 3dMetal Hexafluoroacetylacetonates with 3,5-and 3,6-Di-Tert-Butyl-O-Benzoquinones
Fokin, S. V.
Fursova, E. Yu.
Letyagin, G. A.
Bogomyakov, A. S.
Morozov, V. A.
Romanenko, G. V.
Ovcharenko, V. I.
JOURNAL OF STRUCTURAL CHEMISTRY, 2020, 61 (04) : 541 - 549
[5] 3,6-Di-tert-butylcatecholates of trialkyl/triarylantimony(V)
Poddel'sky, Andrey I.
Smolyaninov, Ivan V.
Fukin, Georgy K.
Berberova, Nadezhda T.
Cherkasov, Vladimir K.
Abakumov, Gleb A.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2018, 867 : 238 - 245
[6] Structural Diversity of Calcium, Strontium, and Barium Complexes with Reduced Forms of the 3,6-Di-tert-butyl-o-benzoquinone Ligand
Sinitsa, Dmitry K.
Sukhikh, Taisiya S.
Petrov, Pavel A.
Nadolinny, Vladimir A.
Konchenko, Sergey N.
Pushkarevsky, Nikolay A.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 2019 (39-40) : 4373 - 4383
[7] Zinc and cadmium complexes based on 3,6-di-tert-butyl-o-benzoquinone
Piskunov, A. V.
Maleeva, A. V.
Abakumov, G. A.
Cherkasov, V. K.
Fukin, G. K.
Bogomyakov, A. S.
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2011, 37 (04) : 243 - 256
[8] Photooxygenolysis of 3,6-di-tert-butyl-o-benzoquinone
Vol'eva, VB
Belostotskaya, IS
Komissarova, NL
Starikova, ZA
Kurkovskaya, LN
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2006, 42 (02) : 227 - 229
[9] Photooxygenolysis of 3,6-di-tert-butyl-o-benzoquinone
V. B. Vol’eva
I. S. Belostotskaya
N. L. Komissarova
Z. A. Starikova
L. N. Kurkovskaya
Russian Journal of Organic Chemistry, 2006, 42 : 227 - 229
[10] Dehydrogenative Dimerization of Di-tert-butyltin Dihydride Photochemically and Thermally Catalyzed by Iron and Molybdenum Complexes
Sharma, Hemant K.
Arias-Ugarte, Renzo
Metta-Magana, Alejandro J.
Pannell, Keith H.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (34) : 6309 - 6312

← 1 2 3 4 5 →