Fabrication of MOF Thin Films at Miscible Liquid Liquid Interface by Spray Method

被引：86

作者：

Bai, Xiao-jue ^{[1
]}

Chen, Dan ^{[1
]}

Li, Lin-lin ^{[1
]}

Shao, Lei ^{[1
]}

He, Wen-xiu ^{[1
]}

Chen, Huan ^{[1
]}

Li, Yu-nong ^{[1
]}

Zhang, Xue-min ^{[1
]}

Zhang, Li-ying ^{[1
]}

Wang, Tie-qiang ^{[1
]}

Fu, Yu ^{[1
]}

Qi, Wei ^{[2
]}

机构：

[1] Northeastern Univ, Coll Sci, Dept Chem, Shenyang 110819, Liaoning, Peoples R China

[2] Chinese Acad Sci, Shenyang Natl Lab Mat Sci, Inst Met Res, Shenyang 110016, Liaoning, Peoples R China

来源：

ACS APPLIED MATERIALS & INTERFACES | 2018年 / 10卷 / 31期

基金：

中国国家自然科学基金;

关键词：

metal-organic frameworks; thin films; spray technology; miscible liquid-liquid interface synthesis; catalysis membrane reactor; METAL-ORGANIC-FRAMEWORK; LITHIUM-SULFUR BATTERIES; GROWTH; MEMBRANE; COATINGS; STORAGE;

D O I：

10.1021/acsami.8b09812

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Metal-organic frameworks (MOFs) are an intriguing class of porous crystalline inorganic-organic hybrid materials. The fabrication of oriented, crystalline thin film of MOFs is expected to open novel avenues to traditional applications and to serve myriad advanced technologies. Here, a facile spray-assisted miscible liquid-liquid interface (MLLI) synthetic strategy is carried out and reported under mild condition that utilizes miscible interface for the rapid and controllable fabrication of large-area free-standing MOF thin films. The methodology can employ various metal nodes and organic ligands to yield various high quality lamellar/granulous MOF thin films at MLLI, which indicates the universality of the MLLI strategy.

引用

页码：25960 / 25966

页数：7

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