Characterisation of CO2 corrosion scale in simulated solution with Cl- ion under turbulent flow conditions

被引:16
作者
Yin, Z. F. [1 ,2 ]
Zhao, W. Z. [1 ]
Feng, Y. R. [2 ]
Zhu, S. D. [3 ]
机构
[1] Xi An Jiao Tong Univ, Sch Mat Sci & Engn, Xian 710049, Peoples R China
[2] CNPC, Key Lab Mech & Environm Behav Tubular Goods, Tubular Goods Res Ctr, Xian 710065, Peoples R China
[3] Xian Shiyou Univ, Sch Mat Sci & Engn, Xian 710065, Peoples R China
关键词
Corrosion scale; Flow velocity; SEM; X-ray diffraction; X-ray photoelectron spectroscopy; SATURATED NEUTRAL ELECTROLYTE; CARBON-DIOXIDE SOLUTIONS; IRON ELECTRODE; MILD-STEEL; BEHAVIOR; MICROSTRUCTURE; DIFFUSION; MECHANISM; GROWTH; LAYERS;
D O I
10.1179/174327808X303482
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In the present work, characterisations such as surface morphology, cross-section image and composition of corrosion scale formed on the P110 steel under turbulent flow conditions with various Cl- concentrations have been studied by means of scanning electron microscopy, X-ray diffraction and X-ray photoelectron spectroscopy. The corrosion medium was the simulated solution of one oil/gas field, saturated with CO2 at 100 degrees C and 4 MPa. The tests were conducted corresponding to various Cl- concentrations and varied flow velocities. It is concluded that Cl- concentration and flow velocity have an important effect on the corrosion scales formed on the samples. In addition, the protective properties and adherence of the corrosion scales were characterised by the analysis of the scale formation and influence mechanisms associated with Cl- concentration and flow velocity. Moreover, a lattice model is created to interpret and illuminate the corrosion process.
引用
收藏
页码:453 / 461
页数:9
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