On the reaction of [Ph-2(OH)Si](2)O with t-Bu2SnCl2: synthesis and characterization of the first well defined polystannasiloxane [(t-Bu2SnO)(Ph2SiO)(2)](n)

被引：36
作者：
Beckmann, J
Jurkschat, K
Schollmeyer, D
Schurmann, M
机构：
[1] UNIV DORTMUND, LEHRSTUHL ANORGAN CHEM 2, D-44221 DORTMUND, GERMANY
[2] UNIV MAINZ, INST ORGAN CHEM, D-55099 MAINZ, GERMANY
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 543卷 / 1-2期
关键词：
X-ray diffraction; silicon; tin; synthesis; polymer;
D O I：
10.1016/S0022-328X(97)00263-5
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The high yield synthesis of [(t-Bu2SnO)(Ph2SiO)(2)], 1 is reported. Compound 1 is a linear polymer in the solid state but a six-membered ring in solution. (C) 1997 Elsevier Science S.A.
引用
收藏
页码：229 / 232
页数：4
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