A method for determination of retention of silver and cerium oxide manufactured nanoparticles in soils

被引：107

作者：

Cornelis, Geert ^{[1
]}

Kirby, Jason K. ^{[2
]}

Beak, Douglas ^{[2
]}

Chittleborough, David ^{[3
]}

McLaughlin, Mike J. ^{[1
,2
]}

机构：

[1] Univ Adelaide, Sch Food Agr & Wine, Glen Osmond, SA 5064, Australia

[2] CSIRO Land & Water, Ctr Environm Contaminants Res, Glen Osmond, SA 5064, Australia

[3] Univ Adelaide, Sch Earth & Environm Sci, Adelaide, SA 5005, Australia

来源：

ENVIRONMENTAL CHEMISTRY | 2010年 / 7卷 / 03期

基金：

澳大利亚研究理事会;

关键词：

K-d; K-r; partitioning; risk assessment; transport; NATURAL ORGANIC-MATTER; CEO2; NANOPARTICLES; ESCHERICHIA-COLI; WATER; SPECIATION; METALS; TOXICITY; MOBILITY; FATE; NANOMATERIALS;

D O I：

10.1071/EN10013

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Methods to study the retention of manufactured nanoparticles (MNP) are lacking for soils that are likely to be increasingly exposed to MNP. In this study we present, for the first time, a method to determine retention values (K-r) of Ag and CeO2 MNP, that can be ranked among solid-liquid partitioning (K-d) values of bulk (micrometre-sized) forms, soluble salts and other possible contaminants of soils. After method optimisation, suspensions containing 1.24 mg kg(-1) Ag as Ag MNP and 1.30 mg kg(-1) Ce as CeO2 MNP were added to five soils. More than 7% of Ag MNP occurred as soluble Ag-I after 24 h and the range of K-r values of Ag MNP (77-2165 L kg(-1)) and CeO2 MNP(1.1-2828 L kg(-1)) contrasted with K-d values of soluble Ag-I, Ce-III and Ce-IV salts and bulk Ag and CeO2 powders in different soils.

引用

页码：298 / 308

页数：11