Kinetics of oxidation of aliphatic acids by quinolinium dichromate

被引：0

作者：

Suante, H ^{[1
]}

Mahanti, MK ^{[1
]}

机构：

[1] NE Hill Univ, Dept Chem, Shillong 793022, Meghalaya, India

来源：

OXIDATION COMMUNICATIONS | 2004年 / 27卷 / 03期

关键词：

oxidation; acetic acid; propionic acid; butyric acid; quinolinium dichromate;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidation of acetic, propionic and butyric acids by quinolinium dichromate (QDC) gave glyoxylic acid, pyruvic acid and 2-ketobutyric acid, respectively. The rate of the reaction showed a first order dependence on the concentrations of each (QDC, substrate and H+). The mechanism involved the formation of a cyclic chromate ester, which underwent decomposition in a slow step to give the products.

引用

页码：629 / 634

页数：6

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