Palladium-catalyzed synthesis of aqueous, fluorous, and supercritical CO2-soluble phosphines

被引：54

作者：

Chen, WP ^{[1
]}

Xu, LJ ^{[1
]}

Xiao, JL ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Leverhulme Ctr Innovat Catalysis, Liverpool L69 7ZD, Merseyside, England

来源：

ORGANIC LETTERS | 2000年 / 2卷 / 17期

关键词：

D O I：

10.1021/ol006203+

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A generic, simple, and economical route has been developed for the synthesis of phosphines soluble in aqueous, fluorous, and supercritical CO2 phases. The methodology is based on the palladium-catalyzed Heck olefination of haloary/phosphine oxides followed by reduction, affording various arylphosphines in high yields.

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页码：2675 / 2677

页数：3

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