The magnetic susceptibility of ordered and partially disordered manganogrunerites (composition Ca0.1Mn1.9Mg1.25Fe3.562+Fe0.383+Si7.81O22(OH)(2) and Ca0.24Mn1.57Mg2.27Fe2.672+Fe0.323+Si7.84O22(OH)(2)) has been measured between room temperature and 5 K. The influence of disordering of metal cations over the M(1,2,3) sites of the octahedral ribbon in these amphiboles is to dilute Fe2+ within the ribbon. We observe a reduction in both theta(p) and T-N as a hinction of both increased Mg/(Mg+Fe) and metal cation disorder, linked to a reduction in the strength of magnetic coupling between and within the one-dimensional chains of the structure.
机构:
Helmholtz Zentrum Berlin Mat & Energie, D-14109 Berlin, GermanyHelmholtz Zentrum Berlin Mat & Energie, D-14109 Berlin, Germany
Bera, A. K.
Lake, B.
论文数: 0引用数: 0
h-index: 0
机构:
Helmholtz Zentrum Berlin Mat & Energie, D-14109 Berlin, Germany
Tech Univ Berlin, Inst Festkorperphys, D-10623 Berlin, GermanyHelmholtz Zentrum Berlin Mat & Energie, D-14109 Berlin, Germany
Lake, B.
Stein, W. -D.
论文数: 0引用数: 0
h-index: 0
机构:
Helmholtz Zentrum Berlin Mat & Energie, D-14109 Berlin, GermanyHelmholtz Zentrum Berlin Mat & Energie, D-14109 Berlin, Germany
Stein, W. -D.
Zander, S.
论文数: 0引用数: 0
h-index: 0
机构:
Helmholtz Zentrum Berlin Mat & Energie, D-14109 Berlin, GermanyHelmholtz Zentrum Berlin Mat & Energie, D-14109 Berlin, Germany