CsF/[bmim][BF4]: An efficient and reusable system for Henry reaction

被引:13
|
作者
Shinde, Pravin S. [1 ]
Shinde, Sandip S. [1 ]
Dake, Satish A. [1 ]
Sonekar, Vinayak S. [1 ]
Deshmukh, Satish U. [2 ]
Thorat, Vinod V. [2 ]
Andurkar, Narsing M. [1 ]
Pawar, Rajendra P. [2 ]
机构
[1] Dnyanopasak Coll, Dept Chem, Organ Synth Lab, Parbhani 431401, Maharashtra, India
[2] Deogiri Coll, Dept Chem, Aurangabad 431005, Maharashtra, India
关键词
Alkali metals; Cesium fluoride; Ionic liquids; Henry reaction; ELECTRON-POOR ALKENES; IONIC LIQUID; CATALYST; NITROALKANES; BASE; MICHAEL; IMMOBILIZATION; ADDITIONS; FLUORIDE; ALUMINA;
D O I
10.1016/j.arabjc.2010.12.028
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cesium fluorides in ionic liquid [bmim][BF4] have been used to promote the Henry reaction effectively. These reactions proceed smoothly and afford an excellent yield of the products. (C) 2011 Production and hosting by Elsevier B.V. on behalf of King Saud University.
引用
收藏
页码:1013 / 1016
页数:4
相关论文
共 50 条
  • [21] Viscosity of [bmim][PF6] and [bmim][BF4] at High Pressure
    D. Tomida
    A. Kumagai
    K. Qiao
    C. Yokoyama
    International Journal of Thermophysics, 2006, 27
  • [22] Williamson reaction in [bmim][BF4]:: clean and facile synthesis of aryl benzyl ethers
    Wen, XM
    JOURNAL OF CHEMICAL RESEARCH, 2005, (10) : 663 - 664
  • [24] Doebner condensation in ionic liquids [Bmim]BF4 and [Bpy]BF4 to synthesize α, β-unsaturated carboxylic acid
    Jiang, Dong
    Wang, Yuan Yuan
    Xu, Yan Nan
    Dai, Li Yi
    CHINESE CHEMICAL LETTERS, 2009, 20 (03) : 279 - 282
  • [25] Enantioselective hydrogenation in ionic liquids:: Recyclability of the [Rh(COD)(DIPAMP)]BF4 catalyst in [bmim][BF4]
    Frater, Tamas
    Gubicza, Laszlo
    Szollosy, Aron
    Bakos, Jozsef
    INORGANICA CHIMICA ACTA, 2006, 359 (09) : 2756 - 2759
  • [26] Thermodynamic investigations of excess heat capacities of ternary liquid mixtures containing [Bmmim][BF4] + [Bmim][BF4] or [Emim][BF4] + cyclopentanone or cyclohexanone
    Gupta, Heena
    Malik, Sunita
    Chandrasekhar, Masta
    Sharma, Vinod Kumar
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2018, 131 (02) : 1653 - 1669
  • [27] Hydrogen-bonding interactions between [BMIM][BF4] and dimethyl sulfoxide
    Zheng, Yan-Zhen
    He, Hong-Yan
    Zhou, Yu
    Yu, Zhi-Wu
    JOURNAL OF MOLECULAR STRUCTURE, 2014, 1069 : 140 - 146
  • [28] A simple and efficient PTT-mediated synthesis of α-azidoketones in [bmim][BF4] ionic liquid
    Kumar, Anil
    Ahmed, Israr
    Rao, M. Sudershan
    Patel, Gautam
    Kumar, Dalip
    INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY, 2009, 48 (04): : 611 - 616
  • [29] [Bmim]BF4 ionic liquid:: A novel and recyclable reaction media for the synthesis of homoallylic amines
    Yadav, JS
    Reddy, BVS
    Raju, AK
    SYNTHESIS-STUTTGART, 2003, (06): : 883 - 886
  • [30] pH of toluene in [Bmim][BF4] and [Bmim][PF6] ionic liquids
    Ren, Ailing
    Zhang, Dandan
    Duan, Erhong
    Guo, Bin
    Chen, Jianzhong
    BIOTECHNOLOGY, CHEMICAL AND MATERIALS ENGINEERING, PTS 1-3, 2012, 393-395 : 1328 - +