Propane-fed Solid Oxide Fuel Cell Based on a Composite Ni-La-CGO Anode Catalyst

被引:17
|
作者
Lo Faro, Massimiliano [1 ]
La Rosa, Daniela [1 ]
Frontera, Patrizia [2 ]
Antonucci, PierLuigi [2 ]
Antonucci, Vincenzo [1 ]
Arico, Antonino Salvatore [1 ]
机构
[1] CNR ITAE Inst, I-98126 Messina, Italy
[2] Univ Reggio Calabria, Dept Mat & Mech, Calabria, Italy
关键词
Solid oxide fuel cells; Portable power sources; La(2)NiO(4); Autothermal reforming; Propane oxidation; Impedance spectroscopy; INTERMEDIATE TEMPERATURE; DIRECT OXIDATION; SOFC SYSTEM; METHANE; PEROVSKITE; HYDROGEN; ELECTROOXIDATION; HYDROCARBONS; PERFORMANCE; STEAM;
D O I
10.1007/s10562-010-0295-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A composite Ni-La-Ce(0.8)Gd(0.2)O(2) catalyst was investigated for the autothermal reforming of propane. A stable performance was recorded during a 100 h endurance test with a syngas yield of 85% at 800 degrees C. The catalyst was also investigated as anode for the direct utilization of propane in solid oxide fuel cells (SOFCs). This catalyst appeared less affected by carbon deposition during SOFC operation than conventional Ni-cermets.
引用
收藏
页码:57 / 64
页数:8
相关论文
共 50 条
  • [1] Propane-fed Solid Oxide Fuel Cell Based on a Composite Ni-La-CGO Anode Catalyst
    Massimiliano Lo Faro
    Daniela La Rosa
    Patrizia Frontera
    PierLuigi Antonucci
    Vincenzo Antonucci
    Antonino Salvatore Aricò
    Catalysis Letters, 2010, 136 : 57 - 64
  • [2] Electrochemical investigation of a propane-fed solid oxide fuel cell based on a composite Ni-perovskite anode catalyst
    Lo Faro, Massimiliano
    La Rosa, Daniela
    Nicotera, Isabella
    Antonucci, Vincenzo
    Arico, Antonino Salvatore
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2009, 89 (1-2) : 49 - 57
  • [3] Electrochemical behaviour of propane-fed solid oxide fuel cells based on low Ni content anode catalysts
    Lo Faro, M.
    La Rosa, D.
    Nicotera, I.
    Antonucci, V.
    Arico, A. S.
    ELECTROCHIMICA ACTA, 2009, 54 (22) : 5280 - 5285
  • [4] Investigation of Ni-based alloy/CGO electro-catalysts as protective layer for a solid oxide fuel cell anode fed with ethanol
    Lo Faro, M.
    Reis, R. M.
    Saglietti, G. G. A.
    Zignani, S. C.
    Trocino, S.
    Frontera, P.
    Antonucci, P. L.
    Ticianelli, E. A.
    Arico, A. S.
    JOURNAL OF APPLIED ELECTROCHEMISTRY, 2015, 45 (07) : 647 - 656
  • [5] Modeling of Ni-CGO anode in a solid oxide fuel cell deposited by spray pyrolysis
    Liu, Lin
    Kim, Gap-Yong
    Chandra, Abhijit
    JOURNAL OF POWER SOURCES, 2012, 210 : 129 - 137
  • [6] Stability of solid oxide fuel cell anodes based on YST-SDC composite with Ni catalyst
    Puengjinda, Pramote
    Muroyama, Hiroki
    Matsui, Toshiaki
    Eguchi, Koichi
    JOURNAL OF POWER SOURCES, 2012, 216 : 409 - 416
  • [7] Investigation of Ni-based alloy/CGO electro-catalysts as protective layer for a solid oxide fuel cell anode fed with ethanol
    M. Lo Faro
    R. M. Reis
    G. G. A. Saglietti
    S. C. Zignani
    S. Trocino
    P. Frontera
    P. L. Antonucci
    E. A. Ticianelli
    A. S. Aricò
    Journal of Applied Electrochemistry, 2015, 45 : 647 - 656
  • [8] Investigation composite Ni-doped perovskite anode catalyst for electrooxidation of hydrogen in solid oxide fuel cell
    Brunaccini, Giovanni
    Lo Faro, Massimiliano
    La Rosa, Daniela
    Antonucci, Vincenzo
    Arico, Antonino Salvatore
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (12) : 3150 - 3152
  • [9] Preparation of La/Co/Ni-based anode catalyst for biogas-fueled solid oxide fuel cells
    Ngoc Thi Quynh Nguyen
    Tuan Anh Trieu
    Yoon, Hyon Hee
    JOURNAL OF ELECTROCERAMICS, 2015, 35 (1-4) : 75 - 80
  • [10] Nickel-Iron/Gadolinium-Doped Ceria (CGO) Composite Electrocatalyst as a Protective Layer for a Solid-Oxide Fuel Cell Anode Fed with Biofuels
    Lo Faro, Massimiliano
    Trocino, Stefano
    Zignani, Sabrina Campagna
    Italiano, Cristina
    Reis, Rafael Machado
    Ticianelli, Edson Antonio
    Arico, Antonino Salvatore
    CHEMCATCHEM, 2016, 8 (03) : 648 - 655