Recent Advances in Direct Catalytic Dehydrative Substitution of Alcohols

被引:156
作者
Dryzhakov, Marian
Richmond, Edward
Moran, Joseph [1 ]
机构
[1] Univ Strasbourg, ISIS, 8 Alle Gaspard Monge, F-67000 Strasbourg, France
来源
SYNTHESIS-STUTTGART | 2016年 / 48卷 / 07期
关键词
dehydrative substitution; carbocations; homogeneous catalysis; asymmetric catalysis; ASYMMETRIC ALLYLIC ALKYLATION; ENANTIOSELECTIVE PROPARGYLIC ALKYLATION; DIRECT ALPHA-ALKYLATION; CHIRAL PHOSPHORIC-ACID; FRIEDEL-CRAFTS ALKYLATIONS; PI-ACTIVATED ALCOHOLS; C-O BOND; BRONSTED-ACID; NUCLEOPHILIC-SUBSTITUTION; AROMATIC-COMPOUNDS;
D O I
10.1055/s-0035-1560396
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
This review describes methods for the direct catalytic dehydrative substitution of alcohols in the absence of stoichiometric activating agents, excluding methods that involve transfer hydrogenation. Although some earlier literature is discussed, this review mainly covers literature published from 2010 through August 2015.
引用
收藏
页码:935 / 959
页数:25
相关论文
共 239 条
[1]   Etherification reactions of propargylic alcohols catalyzed by a cationic ruthenium allenylidene complex [J].
Alkhaieeli, Doaa F. ;
Baum, Kevin J. ;
Rabus, Jordan M. ;
Bauer, Eike B. .
CATALYSIS COMMUNICATIONS, 2014, 47 :45-48
[2]   BrOnsted Acid-Catalyzed Cascade Reactions Involving 1,2-Indole Migration [J].
Alvarez, Estela ;
Nieto Faza, Olalla ;
Silva Lopez, Carlos ;
Fernandez-Rodriguez, Manuel A. ;
Sanz, Roberto .
CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (37) :12889-12893
[3]  
Anschutz R, 1903, LIEBIGS ANN CHEM, V327, P218
[4]   Chirality Transfer in Au-Catalyzed Cyclization Reactions of Monoallylic Diols: Selective Access to Specific Enantiomers Based on Olefin Geometry [J].
Aponick, Aaron ;
Biannic, Berenger .
ORGANIC LETTERS, 2011, 13 (06) :1330-1333
[5]   The Catalytic Amination of Alcohols [J].
Baehn, Sebastian ;
Imm, Sebastian ;
Neubert, Lorenz ;
Zhang, Min ;
Neumann, Helfried ;
Beller, Matthias .
CHEMCATCHEM, 2011, 3 (12) :1853-1864
[6]   Allylic Alcohols: Sustainable Sources for Catalytic Enantioselective Alkylation Reactions [J].
Bandini, Marco .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (05) :994-995
[7]   π-Activated alcohols: an emerging class of alkylating agents for catalytic Friedel-Crafts reactions [J].
Bandini, Marco ;
Tragni, Michele .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2009, 7 (08) :1501-1507
[8]   Cooperative Catalysis by Palladium and a Chiral Phosphoric Acid: Enantioselective Amination of Racemic Allylic Alcohols [J].
Banerjee, Debasis ;
Junge, Kathrin ;
Beller, Matthias .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (48) :13049-13053
[9]   Solvent-free Bronsted acid catalysed alkylation of arenes and heteroarenes with benzylic alcohols [J].
Barbero, Margherita ;
Cadamuro, Silvano ;
Dughera, Stefano ;
Rucci, Marta ;
Spano, Giulia ;
Venturello, Paolo .
TETRAHEDRON, 2014, 70 (09) :1818-1826
[10]   Iron(III) catalysed synthesis of unsymmetrical di and trisubstituted ureas - a variation of classical Ritter reaction [J].
Basavaprabhu, Hosamani ;
Sureshbabu, Vommina V. .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2012, 10 (13) :2528-2533