Synthesis and Characterization of Palladium(II) CNC Pincer Complexes with Novel Bis(1,2,3-triazolylidene)amine Ligands

被引：6

作者：

Li, Linfeng ^{[1
]}

Cao, Lei ^{[1
]}

Yan, Xiaoyu ^{[1
]}

机构：

[1] Renmin Univ China, Dept Chem, Beijing 100872, Peoples R China

来源：

CHEMISTRYSELECT | 2018年 / 3卷 / 38期

基金：

中国国家自然科学基金;

关键词：

palladium; pincer ligands; transmetalation; 1,2,3-triazolylidene; HETEROCYCLIC CARBENE COMPLEXES; TRANSITION-METAL-COMPLEXES; CATALYTIC-ACTIVITY; BOND ACTIVATION; NHC LIGANDS; RUTHENIUM(II) COMPLEXES; REDUCTIVE ELIMINATION; MECHANISTIC INSIGHTS; N-H; HYDROGENATION;

D O I：

10.1002/slct.201802645

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel CNC pincer ligand with secondary amine moiety flanked by 1,2,3-triazolylidene was reported. Metalation of the ligand precursors with silver oxide afforded the bimetallic silver complexes, which were subsequently transmetalated with palladium to afford palladium(II) CNC Pincer complexes. The structure of these metal complexes was confirmed by X-ray diffraction analyses.

引用

页码：10706 / 10710

页数：5

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