Highly flexible, conductive and transparent PEDOT:PSS/Au/PEDOT:PSS multilayer electrode for optoelectronic devices

被引:28
作者
Aleksandrova, Mariya [1 ]
Videkov, Valentin [1 ]
Ivanova, Radost [1 ]
Singh, Ajaya K. [2 ]
Thool, Gautam Sheel [3 ]
机构
[1] Tech Univ Sofia, Dept Microelect, Kl Ohridski Blvd 8, Sofia 1000, Bulgaria
[2] Govt VYTPG Autonomous Coll, Dept Chem, Durg 491001, India
[3] Indian Inst Chem Technol, CSIR, Inorgan & Phys Chem Div, Uppal Rd, Hyderabad 500007, Andhra Pradesh, India
关键词
Flexible substrate; ITO-free transparent electrode; PEDOT:PSS films; PEDOT:PSS/Au/PEDOT:PSS electrode; optoelectronic devices; ISLAND FILMS; MICROPARTICLES; ULTRATHIN; SURFACE; LAYER;
D O I
10.1016/j.matlet.2016.03.127
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The electrical, optical and bending characteristics of poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS)/Au/PEDOT:PSS deposited on polyethylene terephthalate (PET) substrate were studied as a function of inserted Au film thickness. The results were compared with those of indium-tin oxide (ITO) and single layer PEDOT: PSS electrodes. It was found that insertion of Au film with optimized thickness between PEDOT:PSS layers improved the sheet resistance in comparison to single PEDOT:PSS film and ITO film. It was demonstrated that PEDOT: PSS(35 nm)/Au(15 nm)//PEDOT: PSS(35 nm) exhibits sheet resistance of 20.9 Omega/sq and maximum optical transmission of 82.6% in the visible region. Moreover, this multilayer electrode showed dramatically improved mechanical stability compared to ITO, when subjected to multiple bends. Its sheet resistance variation was 3.8% after applying 2000 bending cycles at radius of curvature 6 mm in comparison to 6.7% for single PEDOT: PSS film and 11.4% for ITO. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:204 / 208
页数:5
相关论文
共 33 条
[1]   Highly flexible, conductive and transparent MoO3/Ag/MoO3 multilayer electrode for organic photovoltaic cells [J].
Abachi, T. ;
Cattin, L. ;
Louarn, G. ;
Lare, Y. ;
Bou, A. ;
Makha, M. ;
Torchio, P. ;
Fleury, M. ;
Morsli, M. ;
Addou, M. ;
Bernede, J. C. .
THIN SOLID FILMS, 2013, 545 :438-444
[2]   Material alternative to ITO for transparent conductive electrode in flexible display and photovoltaic devices [J].
Aleksandrova, Mariya ;
Kurtev, Nikolay ;
Videkov, Valentin ;
Tzanova, Slavka ;
Schintke, Silvia .
MICROELECTRONIC ENGINEERING, 2015, 145 :112-116
[3]   XPS STUDIES OF THE OXYGEN-1S AND OXYGEN-2S LEVELS IN A WIDE-RANGE OF FUNCTIONAL POLYMERS [J].
BRIGGS, D ;
BEAMSON, G .
ANALYTICAL CHEMISTRY, 1993, 65 (11) :1517-1523
[4]   On the ultrathin gold film used as buffer layer at the transparent conductive anode/organic electron donor interface [J].
Cattin, L. ;
Tougaard, S. ;
Stephant, N. ;
Morsli, S. ;
Bernede, J. C. .
GOLD BULLETIN, 2011, 44 (04) :199-205
[5]   Micro-textured conductive polymer/silicon heterojunction photovoltaic devices with high efficiency [J].
Chen, Ting-Gang ;
Huang, Bo-Yu ;
Chen, En-Chen ;
Yu, Peichen ;
Meng, Hsin-Fei .
APPLIED PHYSICS LETTERS, 2012, 101 (03)
[6]   Conductivity enhancement of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) films post-spincasting [J].
Farah, Abdiaziz A. ;
Rutledge, Steven A. ;
Schaarschmidt, Antje ;
Lai, Roger ;
Freedman, Justin P. ;
Helmy, Amr S. .
JOURNAL OF APPLIED PHYSICS, 2012, 112 (11)
[7]   Highly Conductive Transparent Organic Electrodes with Multilayer Structures for Rigid and Flexible Optoelectronics [J].
Guo, Xiaoyang ;
Liu, Xingyuan ;
Lin, Fengyuan ;
Li, Hailing ;
Fan, Yi ;
Zhang, Nan .
SCIENTIFIC REPORTS, 2015, 5
[8]   Frontier of transparent conductive oxide thin films [J].
Hosono, H ;
Ohta, H ;
Orita, M ;
Ueda, K ;
Hirano, M .
VACUUM, 2002, 66 (3-4) :419-425
[9]   Synthesis of Semiconducting Polymer Microparticles as Solid Ionophore with Abundant Complexing Sites for Long-Life Pb(II) Sensors [J].
Huang, Mei-Rong ;
Ding, Yong-Bo ;
Li, Xin-Gui ;
Liu, YingJun ;
Xi, Kai ;
Gao, Chen-Long ;
Kumar, R. Vasant .
ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (24) :22096-22107
[10]   Combinatorial Screening of Potentiometric Pb(II) Sensors from Polysulfoaminoanthraquinone Solid Ionophore [J].
Huang, Mei-Rong ;
Ding, Yong-Bo ;
Li, Xin-Gui .
ACS COMBINATORIAL SCIENCE, 2014, 16 (03) :128-138