catena-poly[[(pyridin-4-ol-κN)-silver(I)]-μ-pyridin-4-olato-κ2N:O]

被引：5

作者：

Gao, S ^{[1
]}

Lu, ZZ ^{[1
]}

Huo, LH ^{[1
]}

Zhao, H ^{[1
]}

机构：

[1] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2004年 / 60卷

关键词：

D O I：

10.1107/S0108270104026757

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title complex, [Ag(C5H4NO)(C5H5NO)](n), consists of a polymeric neutral chain involving both a neutral pyridin-4-ol ligand and a deprotonated pyridin-4-olate monoanion. The Ag-I atom shows a T-shaped coordination geometry, defined by one N atom of the pyridin-4-ol and one O and one N atom of two independent pyridin-4-olate bridges; the N - Ag - N moiety is approximately linear. The polymeric chains are connected via strong O - H ... O hydrogen bonds and offset pi-pi interactions into a three-dimensional network.

引用

页码：M651 / M653

页数：3

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