catena-poly[[(pyridin-4-ol-κN)-silver(I)]-μ-pyridin-4-olato-κ2N:O]

被引:5
作者
Gao, S [1 ]
Lu, ZZ [1 ]
Huo, LH [1 ]
Zhao, H [1 ]
机构
[1] Heilongjiang Univ, Sch Chem & Mat Sci, Harbin 150080, Peoples R China
关键词
D O I
10.1107/S0108270104026757
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The title complex, [Ag(C5H4NO)(C5H5NO)](n), consists of a polymeric neutral chain involving both a neutral pyridin-4-ol ligand and a deprotonated pyridin-4-olate monoanion. The Ag-I atom shows a T-shaped coordination geometry, defined by one N atom of the pyridin-4-ol and one O and one N atom of two independent pyridin-4-olate bridges; the N - Ag - N moiety is approximately linear. The polymeric chains are connected via strong O - H ... O hydrogen bonds and offset pi-pi interactions into a three-dimensional network.
引用
收藏
页码:M651 / M653
页数:3
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