Mesoporous templated silicates: an overview of their synthesis, catalytic activation and evaluation of the stability

被引:172
作者
Linssen, T [1 ]
Cassiers, K [1 ]
Cool, P [1 ]
Vansant, EF [1 ]
机构
[1] Dept Chem, Lab Adsorpt & Catalysis, B-2610 Antwerp, Belgium
关键词
mesoporous materials; synthesis; characterization; catalysis;
D O I
10.1016/S0001-8686(02)00084-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The most recent developments in the formation of new mesoporous templated zeolitic materials, characterized by surfaces of more than 1000 m(2)/g, are discussed in this paper. By adapting the synthesis parameters, such as type of silicium source, type of template, pH, temperature,... different materials can be synthesized with varying porosity and crystallinity. Besides the synthesis, much attention is focused on the activation of their surfaces by incorporation methods or deposition processes towards catalytic applications. Finally, the stability of the different materials, one of the critical parameters to potential industrial applications, is compared and evaluated. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:121 / 147
页数:27
相关论文
共 199 条
[1]   Enhanced Bronsted acidity created upon Al-grafting of porous clay heterostructures via aluminium acetylacetonate adsorption [J].
Ahenach, J ;
Cool, P ;
Vansant, EF .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2000, 2 (24) :5750-5755
[2]  
[Anonymous], Google Patents, Patent No. [US5098684A, 5098684]
[3]   Simultaneous modification of mesopores and extraction of template molecules from MCM-41 with trialkylchlorosilanes [J].
Antochshuk, V ;
Jaroniec, M .
CHEMICAL COMMUNICATIONS, 1999, (23) :2373-2374
[4]   TEMPLATING OF MESOPOROUS MOLECULAR-SIEVES BY NONIONIC POLYETHYLENE OXIDE SURFACTANTS [J].
BAGSHAW, SA ;
PROUZET, E ;
PINNAVAIA, TJ .
SCIENCE, 1995, 269 (5228) :1242-1244
[5]   Preparation of metal-incorporated MSU mesoporous silica molecular sieves. Ti incorporation via a totally non-ionic route [J].
Bagshaw, SA ;
DiRenzo, F ;
Fajula, F .
CHEMICAL COMMUNICATIONS, 1996, (18) :2209-2210
[6]   Supported tantalum oxide and supported vanadia-tantala mixed oxides:: Structural characterization and surface properties [J].
Baltes, M ;
Kytökivi, A ;
Weckhuysen, BM ;
Schoonheydt, RA ;
Van Der Voort, P ;
Vansant, EF .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (26) :6211-6220
[7]   The adsorption of VO(acac)2 on a mesoporous silica support by liquid phase and gas phase modification to prepare supported vanadium oxide catalysts [J].
Baltes, M ;
Van Der Voort, P ;
Collart, O ;
Vansant, EF .
JOURNAL OF POROUS MATERIALS, 1998, 5 (3-4) :317-324
[8]  
Barrer RM., 1982, HYDROTHERMAL CHEM ZE
[9]   MOLECULAR OR SUPRAMOLECULAR TEMPLATING - DEFINING THE ROLE OF SURFACTANT CHEMISTRY IN THE FORMATION OF MICROPOROUS AND MESOPOROUS MOLECULAR-SIEVES [J].
BECK, JS ;
VARTULI, JC ;
KENNEDY, GJ ;
KRESGE, CT ;
ROTH, WJ ;
SCHRAMM, SE .
CHEMISTRY OF MATERIALS, 1994, 6 (10) :1816-1821
[10]   A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].
BECK, JS ;
VARTULI, JC ;
ROTH, WJ ;
LEONOWICZ, ME ;
KRESGE, CT ;
SCHMITT, KD ;
CHU, CTW ;
OLSON, DH ;
SHEPPARD, EW ;
MCCULLEN, SB ;
HIGGINS, JB ;
SCHLENKER, JL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843