Study of novel fluorescent probes using twisted intramolecular charge transfer

被引：0

作者：

Wei, SL ^{[1
]}

Lu, JZ ^{[1
]}

Jiang, YB ^{[1
]}

Xu, JG ^{[1
]}

机构：

[1] Xiamen Univ, Dept Chem, Res Lab SEDC Analyt Sci Mat & Life Chem, Xiamen 361005, Peoples R China

来源：

ACTA CHIMICA SINICA | 1998年 / 56卷 / 01期

关键词：

twisted intramolecular charge transfer; sodium p-Ni; N-diethylaminobenzoate; sodium p-N; N-dimethylaminobenzoate; methylated beta-cyclodextrin; determination of methanol;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The change in cave micro-invironment of beta-cyclodextrin (beta-CD) caused by methylation was Investigated by using the twisted intramolecular charge transfer (TICT) of sodium diethylaminobenzoate (SDEAB) and sodium dimethylaminobenzoate (SDMAB) as fluorescent probes. The results indicate that the nonpolar beta-CD cavity favors the formation of the TICT state of dialkylaminobenzoic acid-type molecules. It was demonstrated that the TICT fluorescence of SDEAB (or SDMAB)-beta-MCD (methylated beta-cyclodextrin) system could be used to detect methanol in aqueous solution.

引用

页码：37 / 40

页数：4

共 9 条

[1] GRABOWSKI ZR, 1979, NOUV J CHIM, V3, P443
[2] JIANG YB, 1993, ACTA CHIM SINICA, V51, P748
[3] FLUORESCENCE SPECTROSCOPIC INVESTIGATION OF THE EFFECT OF ALPHA-CYCLODEXTRIN ON THE TWISTED INTRAMOLECULAR CHARGE-TRANSFER OF P-DIMETHYLAMINOBENZOIC ACID IN AQUEOUS-MEDIA
JIANG, YB
[J]. APPLIED SPECTROSCOPY, 1994, 48 (09) : 1169 - 1173
[4] JIANG YB, 1993, SCI CHINA SER B, V23, P71
[5] JIANG YB, 1994, CHINESE SCI BULL, V39, P799
[6] Effects of Aliphatic Alcohol on the Twisted Intramolecular Charge Transfer in Charged Micelle Studied by Dual Fluorescence
Jiang Yunbao
Wang Xiujuan
[J]. ACTA PHYSICO-CHIMICA SINICA, 1994, 10 (09) : 856 - 859
[7] EFFECT OF CYCLODEXTRINE CAVITY SIZE ON TWISTED INTRAMOLECULAR CHARGE-TRANSFER EMISSION - DIMETHYLAMINO BENZONITRILE IN BETA-CYCLODEXTRINE
NAG, A
DUTTA, R
CHATTOPADHYAY, N
BHATTACHARYYA, K
[J]. CHEMICAL PHYSICS LETTERS, 1989, 157 (1-2) : 83 - 86
[8] CHARGE SEPARATION IN EXCITED-STATES OF DECOUPLED SYSTEMS - TICT COMPOUNDS AND IMPLICATIONS REGARDING THE DEVELOPMENT OF NEW LASER-DYES AND THE PRIMARY PROCESSES OF VISION AND PHOTOSYNTHESIS
RETTIG, W
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (11): : 971 - 988
[9] INTRAMOLECULAR EXCITED-STATE CHARGE-TRANSFER AND FLUORESCENCE DECAY OF PARA-CYANO-N,N-DIMETHYLANILINE IN MIXED HYDROCARBON HALOCARBON SOLVENTS
ROTKIEWICZ, K
KOHLER, G
[J]. JOURNAL OF LUMINESCENCE, 1987, 37 (04) : 219 - 225

← 1 →