Synthesis, characterization and fluorescence spectra of mononuclear Zn(II), Cd(II) and Hg(II) complexes with 1,10-phenanthroline-5,6-dione ligand

被引：7

作者：

Boghaei, Davar M. ^{[1
]}

Behzadian-Asl, Fatemeh ^{[1
]}

机构：

[1] Sharif Univ Technol, Dept Chem, Tehran, Iran

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2007年 / 60卷 / 03期

关键词：

1,10-phenanthroline-5,6-dione; zinc; cadmium; mercury; metal to ligand charge transfer; fluorescence;

D O I：

10.1080/00958970600862151

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mononuclear complexes of Zn(II), Cd(II) and Hg(II), [Zn(phen-dione) Cl-2], [Cd(phendione)Cl-2] and [Hg(phen-dione)Cl-2], where phen-dione 1,10-phenanthroline-5,6-dione, have been synthesized and characterized by elemental analysis and IR, (HNMR)-H-1 and electronic absorption spectroscopies. The v(C=O) of coordinated phen- dione ligands in these complexes shows that the phen- dione is not coordinated to metal ion from its C = O sites. Electronic spectra of the complexes show two absorption bands for intraligand transitions. These absorption bands show dependence on the dielectric constant of solvents. These complexes exhibit an intense fluorescence band around 545 nm in DMSO when the excitation wavelengths are 200 nm at room temperature.

引用

页码：347 / 353

页数：7

共 33 条

[1] Dipyridophenazine complexes of cobalt(III) and nickel(II): DNA-Binding and photocleavage studies [J].